Aerobic Ruthenium-Catalyzed C–H Activations
von Alexander Bechtoldt
Datum der mündl. Prüfung:2018-08-17
Erschienen:2018-08-31
Betreuer:Prof. Dr. Lutz Ackermann
Gutachter:Prof. Dr. Lutz Ackermann
Gutachter:Prof. Dr. Konrad Koszinowski
Gutachter:Prof. Dr. Manuel Alcarazo
Gutachter:Prof. Dr. Dietmar Stalke
Gutachter:Dr. Franziska Thomas
Gutachter:Dr. Max Hansmann
Dateien
Name:Dissertation Alex Bechtoldt.pdf
Size:8.27Mb
Format:PDF
Description:Dissertation
Zusammenfassung
Englisch
Within the last decades C–H activation processes have evolved from a promising concept to a powerful class of reactions for the construction of organic molecules, especially pharmaceutically active compounds. Within this thesis, new and improved synthetic transformations based on C–H activation by ruthenium(II) catalysis, in combination with the use of renewable chemicals, were developed. Additionally, a catalyst system for the effective hydrogen isotope exchange (HIE) on alkenes was explored.
Keywords: C–H Activation; Ruthenium(II) catalysis; Green solvents; Green Chemistry; Alkenylation; Hydrogen Isotope Exchange (HIE)