Advanced NMR Methodology for the Investigation of Organometallic Compounds in Solution

by Ann-Christin Pöppler
Doctoral thesis
Date of Examination:2013-06-24
Date of issue:2013-11-06
Advisor:Prof. Dr. Dietmar Stalke
Referee:Prof. Dr. Dietmar Stalke
Referee:Prof. Dr. Philipp Vana
Persistent Address: http://dx.doi.org/10.53846/goediss-4119

 

 

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Abstract

English

The scope of this thesis was to investigate organometallic compounds by advanced solution state NMR methods in order to build a bridge from known solid state structures to their behaviour in solution. Since these reagents are mostly applied in solution, knowledge of the structural motives could improve the possibility to tune their reactivity. The projects presented in three separate chapters are dedicated to NMR spectroscopy in isotropic solution, NMR in anisotropic environment and combined approaches.
Keywords: Structure Elucidation by NMR; Lithium; RQCs
 
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