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Ruthenium-Catalyzed Synthesis of Biaryls through C–H Bond Functionalizations

dc.contributor.advisorAckermann, Lutz Prof. Dr.
dc.contributor.authorDiers, Emelyne
dc.date.accessioned2013-11-15T10:14:41Z
dc.date.available2013-11-15T10:14:41Z
dc.date.issued2013-11-15
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-0001-BC4E-F
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-4166
dc.language.isoengde
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540de
dc.titleRuthenium-Catalyzed Synthesis of Biaryls through C–H Bond Functionalizationsde
dc.typedoctoralThesisde
dc.contributor.refereeAckermann, Lutz Prof. Dr.
dc.date.examination2013-10-14
dc.description.abstractengThe main focus of this work was the development of new methodologies for the efficient and step-economical synthesis of biaryls cores by direct arylation through direct C–H bond cleavage. In this aim, the first ruthenium-catalyzed direct arylation of arenes bearing a removable directing group was achieved. Furthermore, a step-economical synthesis to the antihypertensive Valsartan was successful with ruthenium as a catalyst. Afterwards, we developed a new bidentate directing group for the efficient ruthenium-catalyzed direct arylation of amides.de
dc.contributor.coRefereeDiederichsen, Ulf Prof. Dr.
dc.subject.engcatalysisde
dc.subject.engC–H bond functionalizationde
dc.subject.engrutheniumde
dc.subject.engsustainable chemistryde
dc.subject.engbiarylsde
dc.subject.engValsartande
dc.identifier.urnurn:nbn:de:gbv:7-11858/00-1735-0000-0001-BC4E-F-4
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.identifier.ppn771697570


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