Aluminum Compounds with 3,5-Di-tert-butylpyrazolato Ligands: Syntheses, Structures and Reactions

Aluminium Verbindungen mit 3,5-Di-tert-butylpyrazolato Ligand: Synthese, Strukturen und Reaktion

by Wenjun Zheng
Doctoral thesis
Date of Examination:2001-10-30
Date of issue:2002-01-11
Advisor:Prof. Dr. Dr. h.c. Herbert W. Roesky
Referee:Prof. Dr. Dr. h.c. Herbert W. Roesky
Referee:Prof. Dr. Uwe Klingebiel
Persistent Address: http://dx.doi.org/10.53846/goediss-2139

 

 

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Abstract

English

In this doctoral thesis the bulky 3,5-Di-tert-butylpyrazolato ligand was used to synthesize 27 new organoaluminum complexes combined with halide, alkyl, acetylide groups, hydride, chalcogenide. Novel coordination compounds were obtained and structurally characterized by single crystal X-ray structural analysis.
Keywords: Aluminum; Pyrazolato; N-Ligand; Coordination

Other Languages

In dieser Dissertation wird der Einsatz des sperrigen 3,5-Di-tert-butylpyrazolato zur Synthese von 27 verschiedenen Organoaluminium Komplexen in Kombination mit Halogenide, Alkyl, Acetylidegruppen, Hydride and chalcogenide Elemente. Neue Komplexverbindungen wurden dargestellt und mit röntgenografischer Einkristallstrukturanalyse strukturell aufgeklärt
Schlagwörter: Aluminum; Pyrazolato; N-Ligand; Koordination
 
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