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Unprecedented Synthetic and Reactivity Studies of Compounds with Low Valent Group 14 Elements

dc.contributor.advisorRoesky, Herbert W. Prof. Dr. Dr. h.c.de
dc.contributor.authorJana, Anukulde
dc.date.accessioned2010-05-07T15:08:43Zde
dc.date.accessioned2013-01-18T10:41:23Zde
dc.date.available2013-01-30T23:51:25Zde
dc.date.issued2010-05-07de
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-0006-B070-Cde
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-2237
dc.description.abstractMeine Doktorarbeit über die Synthese und Reaktivität der Verbindungen mit geringer wertigen Gruppe 14 Elemente (Kohlenstoff, Silizium, Germanium und Zinn), die Hydrierung von N-heterozyklischen Carbens durch Ammoniak Boran, oxidative Addition von Ammoniak bei der Silizium enthalten (II)-Zentrum, NH-Bindungsspaltung von Ammoniak bei Germanium (II)-Zentrum, Reaktivität der Germylen Hydrid-und stannylen Hydrid, Dehydrierung von Germylen Hydrid durch frustrierte Lewis-Paar Carben Boran, Wasserstoff für die Fluor-Austausch von stannylen Hydrid-, Synthese des ersten monomeren Zinn ( II) hydroxid und auch Synthese neuartiger heteroleptischen Silizium, Germylen und stannylen Verbindungen.de
dc.format.mimetypeapplication/pdfde
dc.language.isoengde
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/de
dc.titleUnprecedented Synthetic and Reactivity Studies of Compounds with Low Valent Group 14 Elementsde
dc.typedoctoralThesisde
dc.contributor.refereeRoesky, Herbert W. Prof. Dr. Dr. h.c.de
dc.date.examination2009-10-22de
dc.subject.dnb540 Chemiede
dc.description.abstractengMy doctoral work based on the synthesis and reactivity of the compounds with low valent group 14 elements (carbon, silicon, germanium, and tin), which include the hydrogenation of N-heterocyclic carbene by ammonia borane, oxidative addition of ammonia at the silicon(II) center, N-H bond cleavage of ammonia at germanium(II) center, reactivity of the germylene hydride and stannylene hydride, dehydrogenation of germylene hydride by frustrated carbene borane Lewis pair, hydrogen for fluorine exchange by stannylene hydride, synthesis of first monomeric tin(II) hydroxide, and also synthesis of novel heteroleptic silicon, germylene, and stannylene compounds.de
dc.contributor.coRefereeStalke, Dietmar Prof. Dr.de
dc.subject.topicMathematics and Computer Sciencede
dc.subject.gerKeywords in German: Carbon (II)de
dc.subject.gerSilizium (II)de
dc.subject.gerGermanium (II) und Zinn (II)de
dc.subject.engCarbon(II)de
dc.subject.engSilicon(II)de
dc.subject.engGermanium(II)de
dc.subject.engand Tin(II)de
dc.subject.bk35.17 Katalysede
dc.subject.bk35.52 Präparative Organische Chemiede
dc.subject.bk35.59 Heterocyclische Verbindungen: Aromatische heterocyclische Verbindungende
dc.identifier.urnurn:nbn:de:gbv:7-webdoc-2449-2de
dc.identifier.purlwebdoc-2449de
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullSU 000 Organische Chemiede
dc.subject.gokfullSUU 000 Heterocyclische Verbindungende
dc.subject.gokfullSUD 900 Synthesen in der organischen Chemiede
dc.identifier.ppn627381782de


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