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Aluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structures

dc.contributor.advisorRoesky, Herbert W. Prof. Dr. Dr. h.c.de
dc.contributor.authorCui, Chunmingde
dc.date.accessioned2001-06-01T15:10:14Zde
dc.date.accessioned2013-01-18T10:35:29Zde
dc.date.available2013-01-30T23:51:01Zde
dc.date.issued2001-06-01de
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-0006-B0E1-Cde
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-2109
dc.format.mimetypeContentType:application/pdf Size:1317de
dc.language.isoengde
dc.rights.urihttp://webdoc.sub.gwdg.de/diss/copyrdiss.htmde
dc.titleAluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structuresde
dc.typedoctoralThesisde
dc.contributor.refereeRoesky, Herbert W. Prof. Dr. Dr. h.c.de
dc.date.examination2001-05-02de
dc.subject.dnb540 Chemiede
dc.description.abstractengIn this dissertation, bulky multidentate ligands 1-aza-allyl, N-functionized aryl, diketiminato were used for the preparation of novel aluminum compounds in all oxidation states. The reactivity of base stabilized aluminum hydrides towards chalcogens were investigated. The reduction of diketiminato aluminum dihalide with potassium afforded the first instance of a carbene analogue of aluminum, whereas similar reduction in the presence of alkynes generated cyclopropene analogues of aluminum. The reactions and structures of these unique species were presented.de
dc.contributor.coRefereeKlingebiel, Uwe Prof. Dr.de
dc.subject.topicMathematics and Computer Sciencede
dc.subject.engaluminumde
dc.subject.eng1-aza-allylde
dc.subject.engarylde
dc.subject.engdiketiminatode
dc.subject.engcarbenede
dc.subject.engcyclopropenede
dc.subject.enghydridede
dc.subject.enghalidede
dc.subject.engreductionde
dc.subject.bk35.60 Metallorganische Verbindungende
dc.identifier.urnurn:nbn:de:gbv:7-webdoc-983-0de
dc.identifier.purlwebdoc-983de
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullST Anorganische Chemiede
dc.identifier.ppn331174561


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