Aluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structures

Cui, Chunming

dc.contributor.advisor	Roesky, Herbert W. Prof. Dr. Dr. h.c.	de
dc.contributor.author	Cui, Chunming	de
dc.date.accessioned	2001-06-01T15:10:14Z	de
dc.date.accessioned	2013-01-18T10:35:29Z	de
dc.date.available	2013-01-30T23:51:01Z	de
dc.date.issued	2001-06-01	de
dc.identifier.uri	http://hdl.handle.net/11858/00-1735-0000-0006-B0E1-C	de
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-2109
dc.format.mimetype	ContentType:application/pdf Size:1317	de
dc.language.iso	eng	de
dc.rights.uri	http://webdoc.sub.gwdg.de/diss/copyrdiss.htm	de
dc.title	Aluminum (I, II, III) Compounds with Multidentate Ligands: Syntheses, Reactivity, and Structures	de
dc.type	doctoralThesis	de
dc.contributor.referee	Roesky, Herbert W. Prof. Dr. Dr. h.c.	de
dc.date.examination	2001-05-02	de
dc.subject.dnb	540 Chemie	de
dc.description.abstracteng	In this dissertation, bulky multidentate ligands 1-aza-allyl, N-functionized aryl, diketiminato were used for the preparation of novel aluminum compounds in all oxidation states. The reactivity of base stabilized aluminum hydrides towards chalcogens were investigated. The reduction of diketiminato aluminum dihalide with potassium afforded the first instance of a carbene analogue of aluminum, whereas similar reduction in the presence of alkynes generated cyclopropene analogues of aluminum. The reactions and structures of these unique species were presented.	de
dc.contributor.coReferee	Klingebiel, Uwe Prof. Dr.	de
dc.subject.topic	Mathematics and Computer Science	de
dc.subject.eng	aluminum	de
dc.subject.eng	1-aza-allyl	de
dc.subject.eng	aryl	de
dc.subject.eng	diketiminato	de
dc.subject.eng	carbene	de
dc.subject.eng	cyclopropene	de
dc.subject.eng	hydride	de
dc.subject.eng	halide	de
dc.subject.eng	reduction	de
dc.subject.bk	35.60 Metallorganische Verbindungen	de
dc.identifier.urn	urn:nbn:de:gbv:7-webdoc-983-0	de
dc.identifier.purl	webdoc-983	de
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	ST Anorganische Chemie	de
dc.identifier.ppn	331174561

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