Kinetik von Atom-Transfer Radikalischen Polymerisationen bis zu hohen Drücken

Morick, Joachim

dc.contributor.advisor	Buback, Michael Prof. Dr.	de
dc.contributor.author	Morick, Joachim	de
dc.date.accessioned	2012-11-02T15:43:59Z	de
dc.date.accessioned	2013-01-18T10:41:41Z	de
dc.date.available	2013-01-30T23:51:25Z	de
dc.date.issued	2012-11-02	de
dc.identifier.uri	http://hdl.handle.net/11858/00-1735-0000-000D-F052-2	de
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-2245
dc.format.mimetype	application/pdf	de
dc.language.iso	ger	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/	de
dc.title	Kinetik von Atom-Transfer Radikalischen Polymerisationen bis zu hohen Drücken	de
dc.type	doctoralThesis	de
dc.title.translated	Kinetics of Atom-Transfer Radical Polymerization up to High Pressure	de
dc.contributor.referee	Buback, Michael Prof. Dr.	de
dc.date.examination	2012-09-26	de
dc.subject.dnb	540 Chemie	de
dc.subject.gok	SW 000	de
dc.subject.gok	SGC 000	de
dc.description.abstracteng	Atom-transfer radical polymerization (ATRP) has been studied up to 2500 bar via online VIS/NIR-spectroscopy to monitor the evolution of both CuII concentration and monomer conversion. ATRP-equilibrium constants have been determined under polymerization conditions (KATRP) and in monomer-free model systems (Kmodel) for several combinations of ligands and initiators. Two branched and two linear ligands have been used. Initiators have been chosen to mimic the structure of a bromine-capped chain-end which occurs during ATRP of styrene, methyl methacrylate (MMA) or n-butyl acrylate (n-BA) with chain length unity. Applying pressure significantly enhances the Kmodel which is adequately represented by the reaction volume, ΔVR, model. The obtained values range from ‒16 cm^3	de
dc.contributor.coReferee	Vana, Philipp Prof. Dr.	de
dc.subject.topic	Chemistry	de
dc.subject.ger	Atom-Transfer Radikalische Polymerisation	de
dc.subject.ger	ATRP	de
dc.subject.ger	Kinetik	de
dc.subject.ger	Methylmethacrylat	de
dc.subject.ger	Styrol	de
dc.subject.ger	Butylacrylat	de
dc.subject.eng	Atom-Transfer Radical Polymerization	de
dc.subject.eng	ATRP	de
dc.subject.eng	kinetics	de
dc.subject.eng	methyl methacrylate	de
dc.subject.eng	styrene	de
dc.subject.eng	butyl acrylate	de
dc.subject.bk	35.13	de
dc.subject.bk	35.80	de
dc.identifier.urn	urn:nbn:de:gbv:7-webdoc-3764-3	de
dc.identifier.purl	webdoc-3764	de
dc.affiliation.institute	Fakultät für Chemie	de
dc.identifier.ppn	731314573	de

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