Synthesis of Organoaluminum Fluorides and of an Oxo-Centered Trinuclear Carboxylate of Aluminum

Synthese von Organoaluminiumfluoriden und eines Oxo-zentrierten trinuklearen Carboxylates des Aluminiums

by Hagen Hatop
Doctoral thesis
Date of Examination:2001-06-28
Date of issue:2001-08-01
Advisor:Prof. Dr. Dr. h.c. Herbert W. Roesky
Referee:Prof. Dr. Dr. h.c. Herbert W. Roesky
Referee:PD Dr. U. Ritter
Persistent Address: http://dx.doi.org/10.53846/goediss-3378

 

 

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Abstract

English

In this doctoral thesis the bulky ligand Tris(trimethylsilyl)methyl was used to synthesize organoaluminum fluorides combined with alkali ions and for preparation of an oxo-centered trinuclear carboxylate of aluminum as the lightest member in the class of ''basic carboxylates''. Novel coordination compounds were obtained.
Keywords: Aluminium; Alkali; Fluorid; Carboxylat; Oxo-zentriert; Koordination

Other Languages

In dieser Dissertation wird der Einsatz des sperrigen Tris(trimethylsilyl)methylliganden zur Synthese von Organoaluminiumfluoriden in Kombination mit Alkaliionen und die Darstellung eines oxo-zentrierten trinuklearen Carboxylates des Aluminium beschrieben, welches das leichteste Mitglied in der Gruppe der ''Basic-Carboxylates'' ist. Neue Komplexverbindungen wurden dargestellt.
Schlagwörter: Aluminum; Alkali; Fluoride; Carboxylate; Oxo-centered; Coordination
 
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