Neue unsymmetrische Pyridazin-verbrückte Pyrazol/NHC-Hybridliganden als Gerüste für multinukleare Übergangsmetallkomplexe – erste Anwendungen in der Katalyse
New Unsymmetrical Pyridazine-bridged Pyrazole/NHC-Hybrid Ligands as Scaffolds for Multinuclear Transition Metal Complexes– First Applications in Catalysis
Wimberg, Jan
Dissertation
Angenommen am:2012-05-22
Erschienen:2013-01-24
Betreuer:Meyer, Franc Prof. Dr.
Gutachter:Meyer, Franc Prof. Dr.
Gutachter:Stalke, Dietmar Prof. Dr.
Zum Verlinken/Zitieren:
http://hdl.handle.net/11858/00-1735-0000-000D-F1A4-4
The synthesis and characterization of pyridazine-bridged NHC/pyrazole ligands providing an NHC as organometallic and a classical N-donor compartment is described. These ligands serve as versatile scaffolds for a variety of homo- and heterometallic silver (I), gold(I) and palladium (II) carbene complexes. The main focus of the dissertation is on the characterization of these complexes through various spectroscopic methods and on the examinations regarding their first possible applications.
