Liganden mit N/S-Donorsets in der Münzmetallchemie: Modellkomplexe für Methanobactin und multinukleare, lumineszierende Pyrazolat-Komplexe

Ligands with N/S-Donorsets in coinage metal chemistry: model complexes for methanobactin and multinuclear, luminescent pyrazolate complexes

by Ann Christin Jahnke
Doctoral thesis
Date of Examination:2012-06-25
Date of issue:2013-03-12
Advisor:Prof. Dr. Franc Meyer
Referee:Prof. Dr. Franc Meyer
Referee:Prof. Dr. Ulf Diederichsen
Persistent Address: http://dx.doi.org/10.53846/goediss-3769

 

 

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Abstract

English

The synthesis and characterization of pyrazolate and oxazolone ligands with attached thioether functions is described. These ligands were used either to synthesize copper(I) complexes as model complex for the methanobactin or to obtain a variety of multinuclear, luminescent coinage metal complexes. The focus of this dissertation is on the characterization of these complexes by various spectroscopic methods and on the investigation regarding their further applications.
Keywords: coinage metal complexes; luminescence; double-crown; pyrazolate; methanobactin; copper(I) complexes; multinuclear
Schlagwörter: Münzmetallchemie; Methanobactin; Kupfer(I) Komplexe; Pyrazolat Komplexe; Lumineszenz; multinuklear; Doppelring
 
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