Rutheniumkatalysierte Addition von nicht aktivierten C(sp²)–H- und C(sp³)–H-Bindungen an Alkene
Ruthenium-catalyzed addition of unactivated C(sp²)–H and C(sp³)–H bonds to alkenes
von Marvin Schinkel
Datum der mündl. Prüfung:2013-04-19
Erschienen:2013-04-30
Betreuer:Prof. Dr. Lutz Ackermann
Gutachter:Prof. Dr. Lutz Ackermann
Gutachter:Prof. Dr. Ulf Diederichsen
Dateien
Name:Dissertation - Marvin Schinkel.pdf
Size:6.28Mb
Format:PDF
Zusammenfassung
Englisch
Novel site-selective carboxylate assisted ruthenium-catalyzed hydroarylations of unactivated alkenes, bearing valuable functional groups, with various (hetero)arenes has been accomplished. And a unprecedented ruthenium based catalytic system for the alpha-alkylation of cyclic amines via C(sp³)–H bond activation was found.
Keywords: hydroarylation; C–H-functionalization; carboxylate assisted; cyclic amines; alkylation; addition to alkene; C(sp²)–H-activation; C(sp³)–H-activation; ruthenium; catalysis