Rutheniumkatalysierte Addition von nicht aktivierten C(sp²)–H- und C(sp³)–H-Bindungen an Alkene

Ruthenium-catalyzed addition of unactivated C(sp²)–H and C(sp³)–H bonds to alkenes

by Marvin Schinkel
Doctoral thesis
Date of Examination:2013-04-19
Date of issue:2013-04-30
Advisor:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Ulf Diederichsen
Persistent Address: http://dx.doi.org/10.53846/goediss-3821

 

 

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Abstract

English

Novel site-selective carboxylate assisted ruthenium-catalyzed hydroarylations of unactivated alkenes, bearing valuable functional groups, with various (hetero)arenes has been accomplished. And a unprecedented ruthenium based catalytic system for the alpha-alkylation of cyclic amines via C(sp³)–H bond activation was found.
Keywords: hydroarylation; C–H-functionalization; carboxylate assisted; cyclic amines; alkylation; addition to alkene; C(sp²)–H-activation; C(sp³)–H-activation; ruthenium; catalysis
 
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