Rutheniumkatalysierte Addition von nicht aktivierten C(sp²)–H- und C(sp³)–H-Bindungen an Alkene

Rutheniumkatalysierte Addition von nicht aktivierten C(sp²)–H- und C(sp³)–H-Bindungen an Alkene

Ruthenium-catalyzed addition of unactivated C(sp²)–H and C(sp³)–H bonds to alkenes

Schinkel, Marvin

Dissertation

Angenommen am: 2013-04-19

Erschienen: 2013-04-30

Betreuer: Ackermann, Lutz Prof. Dr.

Gutachter: Ackermann, Lutz Prof. Dr.

Gutachter: Diederichsen, Ulf Prof. Dr.

Zum Verlinken/Zitieren: http://hdl.handle.net/11858/00-1735-0000-0015-A380-B

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Name: Dissertation - Marvin Schinkel.pdf

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Zusammenfassung

Englisch

Novel site-selective carboxylate assisted ruthenium-catalyzed hydroarylations of unactivated alkenes, bearing valuable functional groups, with various (hetero)arenes has been accomplished. And a unprecedented ruthenium based catalytic system for the alpha-alkylation of cyclic amines via C(sp³)–H bond activation was found.

Keywords: hydroarylation; C–H-functionalization; carboxylate assisted; cyclic amines; alkylation; addition to alkene; C(sp²)–H-activation; C(sp³)–H-activation; ruthenium; catalysis