| dc.contributor.advisor | Troe, Jürgen Prof. Dr. | |
| dc.contributor.author | Tellbach, Elsa | |
| dc.date.accessioned | 2014-02-20T10:21:28Z | |
| dc.date.available | 2014-02-20T10:21:28Z | |
| dc.date.issued | 2014-02-20 | |
| dc.identifier.uri | http://hdl.handle.net/11858/00-1735-0000-0022-5E33-E | |
| dc.identifier.uri | http://dx.doi.org/10.53846/goediss-4379 | |
| dc.language.iso | deu | de |
| dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/ | |
| dc.subject.ddc | 540 | de |
| dc.title | Stoßwellenuntersuchungen und Modellierung der Pyrolyse von Pentafluorethan und 2-H-Heptafluorpropan | de |
| dc.type | doctoralThesis | de |
| dc.title.translated | Shock Wave and Modeling Study of the Pyrolysis of Pentafluoroethane and 2-H-Heptafluoropropane | de |
| dc.contributor.referee | Troe, Jürgen Prof. Dr. | |
| dc.date.examination | 2013-12-13 | |
| dc.description.abstracteng | The pyrolysis of C2HF5 and C3HF7 have been studied in shock waves by monitoring die UV-absorption of CF2 at 248nm and temperatures in the range of 1400 - 2000 K. Ar was used as bath gas with concentrations in the range (2-10) x 10^-5 mol cm^-3. It is shown that the reactions are initiated by C-C bond fission and differing conclusions in the literature can be explained with falloff effects. Quantum-chemical calculations were employed to model the kinetic of primary and secondary reactions in the decomposition mechanisms. | de |
| dc.contributor.coReferee | Schröder, Jörg Prof. Dr. | |
| dc.subject.eng | C2HF5, C3HF7, pyrolysis, shock tube, kinetic modeling, reaction mechanism | de |
| dc.identifier.urn | urn:nbn:de:gbv:7-11858/00-1735-0000-0022-5E33-E-2 | |
| dc.affiliation.institute | Fakultät für Chemie | de |
| dc.subject.gokfull | Chemie (PPN62138352X) | de |
| dc.identifier.ppn | 779001915 | |
| dc.creator.birthname | Rusch | |