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Stoßwellenuntersuchungen und Modellierung der Pyrolyse von Pentafluorethan und 2-H-Heptafluorpropan

dc.contributor.advisorTroe, Jürgen Prof. Dr.
dc.contributor.authorTellbach, Elsa
dc.date.accessioned2014-02-20T10:21:28Z
dc.date.available2014-02-20T10:21:28Z
dc.date.issued2014-02-20
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-0022-5E33-E
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-4379
dc.language.isodeude
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540de
dc.titleStoßwellenuntersuchungen und Modellierung der Pyrolyse von Pentafluorethan und 2-H-Heptafluorpropande
dc.typedoctoralThesisde
dc.title.translatedShock Wave and Modeling Study of the Pyrolysis of Pentafluoroethane and 2-H-Heptafluoropropanede
dc.contributor.refereeTroe, Jürgen Prof. Dr.
dc.date.examination2013-12-13
dc.description.abstractengThe pyrolysis of C2HF5 and C3HF7 have been studied in shock waves by monitoring die UV-absorption of CF2 at 248nm and temperatures in the range of 1400 - 2000 K. Ar was used as bath gas with concentrations in the range (2-10) x 10^-5 mol cm^-3. It is shown that the reactions are initiated by C-C bond fission and differing conclusions in the literature can be explained with falloff effects. Quantum-chemical calculations were employed to model the kinetic of primary and secondary reactions in the decomposition mechanisms.de
dc.contributor.coRefereeSchröder, Jörg Prof. Dr.
dc.subject.engC2HF5, C3HF7, pyrolysis, shock tube, kinetic modeling, reaction mechanismde
dc.identifier.urnurn:nbn:de:gbv:7-11858/00-1735-0000-0022-5E33-E-2
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.identifier.ppn779001915
dc.creator.birthnameRusch


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