Control over assembly and interpenetration of Pd-based coordination cages
von Rongmei Zhu
Datum der mündl. Prüfung:2017-03-24
Erschienen:2017-03-27
Betreuer:Prof. Dr. Guido Clever
Gutachter:Prof. Dr. Guido Clever
Gutachter:Prof. Dr. Franc Meyer
Dateien
Name:Dissertation_RongmeiZhu.pdf
Size:14.0Mb
Format:PDF
Zusammenfassung
Englisch
In the first part, a thermordynamically stable monomeric cage was obtained and the transformation from the monomeric cage to dimeric cage and even to a triple catenane was realized by varying the amount of halide anions. In the second part, a peanut-shape cage and its interpenetration cage were obtained by elongating the backbones. In the last part, two multi-component heteroleptic coordination cages were achieved from two different ligands via side-chain directed complimentary coordination strategy.
Keywords: supramolecular; coordination cage; self-assembly; palladium