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Advanced NMR Techniques for the Investigation of Small Molecules in Solution

dc.contributor.advisorStalke, Dietmar Prof. Dr.
dc.contributor.authorNiklas, Thomas
dc.date.accessioned2017-06-28T09:59:49Z
dc.date.available2017-06-28T09:59:49Z
dc.date.issued2017-06-28
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-0023-3E91-7
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-6377
dc.language.isoengde
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540de
dc.titleAdvanced NMR Techniques for the Investigation of Small Molecules in Solutionde
dc.typedoctoralThesisde
dc.contributor.refereeStalke, Dietmar Prof. Dr.
dc.date.examination2017-06-20
dc.description.abstractengNuclear magnetic resonance (NMR) techniques have been developed and employed to study small molecules in solution. A) Slice-selective excitation (SSE) enables the acquisition of spatially resolved spectra. This has been successfully used in (i) a reaction observation experiment, (ii) a titration experiment and (iii) a qualitative chromatography experiment. B) NMR spectroscopy of molecules within uniaxial environments facilitate the observation of anisotropic interactions. This has been employed to (i) study mechanisms of solute alignment, (ii) perform structure verification via residual dipolar couplings (RDCs) and (iii) perform structure verification via residual quadrupolar couplings (RQCs).de
dc.contributor.coRefereeMeyer, Franc Prof. Dr.
dc.subject.engNMRde
dc.subject.engAnisotropic Interactionsde
dc.subject.engSlice-selective Excitationde
dc.identifier.urnurn:nbn:de:gbv:7-11858/00-1735-0000-0023-3E91-7-6
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.identifier.ppn891220089


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