C−H Alkylations and Alkynylations Using Ruthenium, Nickel and Manganese Complexes

von Zhixiong Ruan
Dissertation
Datum der mündl. Prüfung:2017-10-10
Erschienen:2017-10-17
Betreuer:Prof. Dr. Lutz Ackermann
Gutachter:Prof. Dr. Lutz Ackermann
Gutachter:Prof. Dr. Dietmar Stalke
Zum Verlinken/Zitieren: http://dx.doi.org/10.53846/goediss-6525

 

 

Dateien

Name:PhD_thesis_Zhixiong Ruan_final-web.pdf
Size:9.62Mb
Format:PDF

Lizenzbestimmungen:

Zusammenfassung

Englisch

Transition metal-catalyzed C–H functionalizations have recently emerged as a reliable tool for the efficient chemo- and site-selective construction of C–C and C–Het bonds, which is of major importance for the preparation of pharmaceuticals, agrochemicals and functional materials. Within this thesis, efforts have been devoted to developing new step-economic synthetic methods employing versatile nickel-, manganese(I)-, or ruthenium(II)-catalyzed C–H alkylations and alkynylations.
Keywords: C–H activation; Transition metal catalysis; Alkylation; alkynylation; Chelation; Selectivity
 
Statistik