C−H Alkylations and Alkynylations Using Ruthenium, Nickel and Manganese Complexes

by Zhixiong Ruan
Doctoral thesis
Date of Examination:2017-10-10
Date of issue:2017-10-17
Advisor:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Dietmar Stalke
Persistent Address: http://dx.doi.org/10.53846/goediss-6525

 

 

Files in this item

Name:PhD_thesis_Zhixiong Ruan_final-web.pdf
Size:9.62Mb
Format:PDF

The following license files are associated with this item:

Abstract

English

Transition metal-catalyzed C–H functionalizations have recently emerged as a reliable tool for the efficient chemo- and site-selective construction of C–C and C–Het bonds, which is of major importance for the preparation of pharmaceuticals, agrochemicals and functional materials. Within this thesis, efforts have been devoted to developing new step-economic synthetic methods employing versatile nickel-, manganese(I)-, or ruthenium(II)-catalyzed C–H alkylations and alkynylations.
Keywords: C–H activation; Transition metal catalysis; Alkylation; alkynylation; Chelation; Selectivity
 
Statistik