Domino-Reaktionen mit anti-Carbopalladierungen an Alkinen als Schlüsselschritt und Transformationen von Arylthiocyanaten mit Arinen

Domino-Reaktionen mit anti-Carbopalladierungen an Alkinen als Schlüsselschritt und Transformationen von Arylthiocyanaten mit Arinen

Domino Reactions Featuring an anti-Carbopalladation of Alkynes as Key Step and Transformations of Arylthiocyanates with Arynes

Pawliczek, Martin

Doctoral thesis

Date of Examination: 2015-09-08

Date of issue: 2015-09-09

Advisor: Werz, Daniel Prof. Dr.

Referee: Werz, Daniel Prof. Dr.

Referee: Tietze, Lutz Prof. Dr. Dr. h.c.

Persistent Address: http://hdl.handle.net/11858/00-1735-0000-0023-9614-6

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Abstract

English

The work presents a formal anti-carbopalladation reaction of alkynes imbedded into a domino reaction for the synthesis of oligo cyclic structures. Therefore, intra- as well as intermolecular approaches were performed. Further, arylthiocyanates were applied in a 1,2-thiocyanation of arynes as well as for the sysnthesis of sulfur containing heterocycles.

Keywords: alkyne, anti-Carbopalladation, aryne, arylthiocyanate