Domino-Reaktionen mit anti-Carbopalladierungen an Alkinen als Schlüsselschritt und Transformationen von Arylthiocyanaten mit Arinen

Domino Reactions Featuring an anti-Carbopalladation of Alkynes as Key Step and Transformations of Arylthiocyanates with Arynes

by Martin Pawliczek
Doctoral thesis
Date of Examination:2015-09-08
Date of issue:2015-09-09
Advisor:Prof. Dr. Daniel Werz
Referee:Prof. Dr. Daniel Werz
Referee:Prof. Dr. Dr. h.c. Lutz Tietze
Persistent Address: http://dx.doi.org/10.53846/goediss-5260

 

 

Files in this item

Name:Dissertation Martin Pawliczek 0909.pdf
Size:7.63Mb
Format:PDF

The following license files are associated with this item:

Abstract

English

The work presents a formal anti-carbopalladation reaction of alkynes imbedded into a domino reaction for the synthesis of oligo cyclic structures. Therefore, intra- as well as intermolecular approaches were performed. Further, arylthiocyanates were applied in a 1,2-thiocyanation of arynes as well as for the sysnthesis of sulfur containing heterocycles.
Keywords: alkyne, anti-Carbopalladation, aryne, arylthiocyanate
 
Statistik