Domino-Reaktionen mit anti-Carbopalladierungen an Alkinen als Schlüsselschritt und Transformationen von Arylthiocyanaten mit Arinen
Domino Reactions Featuring an anti-Carbopalladation of Alkynes as Key Step and Transformations of Arylthiocyanates with Arynes
von Martin Pawliczek
Datum der mündl. Prüfung:2015-09-08
Erschienen:2015-09-09
Betreuer:Prof. Dr. Daniel Werz
Gutachter:Prof. Dr. Daniel Werz
Gutachter:Prof. Dr. Dr. h.c. Lutz Tietze
Dateien
Name:Dissertation Martin Pawliczek 0909.pdf
Size:7.63Mb
Format:PDF
Zusammenfassung
Englisch
The work presents a formal anti-carbopalladation reaction of alkynes imbedded into a domino reaction for the synthesis of oligo cyclic structures. Therefore, intra- as well as intermolecular approaches were performed. Further, arylthiocyanates were applied in a 1,2-thiocyanation of arynes as well as for the sysnthesis of sulfur containing heterocycles.
Keywords: alkyne, anti-Carbopalladation, aryne, arylthiocyanate