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Untersuchungen zur Synthese fluoreszenzaktiver aromatischer Polyzyklen durch Palladium-katalysierte Domino-C‒H-Aktivierungen

Investigation of the Synthesis of fluorescent aromatic Polycycles via Palladium-catalyzed domino C‒H-activations

Christoph Eichhorst
Doctoral thesis
Date of Examination: 2014-10-09
Date of issue: 2014-11-18
Advisor: Tietze, Lutz Prof. Dr. Dr. h.c.
Referee: Tietze, Lutz Prof. Dr. Dr. H.c.
Referee: Ackermann, Lutz Prof. Dr.

Persistent Address: http://hdl.handle.net/11858/00-1735-0000-0023-993C-7

 

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Abstract

English

Fluorescent dyes were synthesized via novel fourfold Palladium-catalyzed domino reactions consisting of a Sonogashira reaction, two carbopalladations and a C-H-activation in one domino process.
Keywords: Palladium; Fluorescence; Domino reaction; Direct arylation; C-H-activation; Organic Synthesis; Chemistry

Other Languages

Fluoreszenzfarbstoffe wurden über neuartige Palladium-katalysierte Domino-Reaktionen synthetisiert, die aus einer Sonogshira-Reaktion, zwei Carbopalladierungen und einer C-H-Aktivierung bestanden.
Schlagwörter: Palladium; Fluoreszenz; Domino-Reaktion; Direkte Arylierung; C-H-Aktivierung; Organische Synthese; Chemie
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