| dc.contributor.advisor | Meyer, Franc Prof. Dr. | |
| dc.contributor.author | Dalle, Kristian Erwin | |
| dc.date.accessioned | 2016-10-10T14:16:24Z | |
| dc.date.available | 2016-10-10T14:16:24Z | |
| dc.date.issued | 2016-10-10 | |
| dc.identifier.uri | http://hdl.handle.net/11858/00-1735-0000-002B-7C1A-B | |
| dc.identifier.uri | http://dx.doi.org/10.53846/goediss-5887 | |
| dc.identifier.uri | http://dx.doi.org/10.53846/goediss-5887 | |
| dc.language.iso | eng | de |
| dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject.ddc | 540 | de |
| dc.title | Bioinspired Activation of Oxygen with Pyrazole-Supported Dinuclear Copper Complexes | de |
| dc.type | doctoralThesis | de |
| dc.contributor.referee | Meyer, Franc Prof. Dr. | |
| dc.date.examination | 2014-10-22 | |
| dc.description.abstracteng | A series of compartmental pyrazole-bridging ligands were successfully used to gain insights into copper-mediated dioxygen activation chemistry, and thus expand on the proven potential of these organic scaffolds for emulating features of dinuclear metallobiosites. Several systems were investigated in detail, leading to identification of a novel type of peroxo-dicopper(II) adduct. Crystallographic structural determination revealed an unprecedented cis-μ-1,2-peroxide binding mode of the dioxygen-derived ligand. This in turn results in properties consistent with a computationally proposed enzymatic mechanism for dioxygen activation, and allows for binding of alkali metal cations in both solution and the solid state. | de |
| dc.contributor.coReferee | Diederichsen, Ulf Prof. Dr. | |
| dc.subject.eng | Dinuclear Copper, cis-Peroxo, Pyrazole, Oxygen Activation | de |
| dc.identifier.urn | urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7C1A-B-0 | |
| dc.affiliation.institute | Fakultät für Chemie | de |
| dc.subject.gokfull | Chemie (PPN62138352X) | de |
| dc.identifier.ppn | 869904396 | |