Homogeneous and Heterogeneous Chelation-Assisted Ruthenium(II)-Catalyzed C–H Functionalizations

by Svenja Warratz
Doctoral thesis
Date of Examination:2016-11-18
Date of issue:2017-01-03
Advisor:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Konrad Koszinowski
Referee:Prof. Dr. Dietmar Stalke
Persistent Address: http://dx.doi.org/10.53846/goediss-6057

 

 

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Abstract

English

Ruthenium(II)-catalyzed direct C–H functionalizations have emerged as a powerful tool for organic chemists to construct C–C and C–Het bonds. In order to rationally improve the efficiency of these methods a mechanistic understanding of the underlying reactions is crucial. Within this thesis, studies to delineate the mode of powerful C–H transformations have been performed and new methods based on the principles of green chemistry have been developed.
Keywords: C-H Functionalization; Ruthenium; Catalysis
 
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