• Deutsch
    • English
  • English 
    • Deutsch
    • English
  • Login
Item View 
  •   Home
  • Naturwissenschaften, Mathematik und Informatik
  • Fakultät für Chemie (inkl. GAUSS)
  • Item View
  •   Home
  • Naturwissenschaften, Mathematik und Informatik
  • Fakultät für Chemie (inkl. GAUSS)
  • Item View
JavaScript is disabled for your browser. Some features of this site may not work without it.

N2 Splitting and Functionalization in the Coordination Sphere of Rhenium

by Isabel Christina Scheibel née Klopsch
Doctoral thesis
Date of Examination:2016-12-16
Date of issue:2017-01-12
Advisor:Prof. Dr. Sven Schneider
Referee:Prof. Dr. Sven Schneider
Referee:Prof. Dr. Franc Meyer
crossref-logoPersistent Address: http://dx.doi.org/10.53846/goediss-6070

 

 

Files in this item

Name:Dissertation_final.pdf
Size:10.6Mb
Format:PDF
Description:Dissertation
ViewOpen

The following license files are associated with this item:


Abstract

English

The first example of homogeneous N2 splitting mediated by rhenium as group 7 transition metal is reported and represents rare complete scission of the N-N bond in well-defined terminal nitrido complexes. These could be alkylated with electrophiles to imido complexes. Further functionalizations transform the nitrogen containing moeity into organonitriles under recovery of the starting material. Therefore, a synthetic cycle for the transformation of N2 into nitriles comprising three reaction steps is closed. Synthesis, characterization and reactivity of all involved complexes is presented.
Keywords: N2 splitting; rhenium; nitrogen fixation; small molecule activation; acetonitrile; pincer ligands
 

Statistik

Publish here

Browse

All of eDissFaculties & ProgramsIssue DateAuthorAdvisor & RefereeAdvisorRefereeTitlesTypeThis FacultyIssue DateAuthorAdvisor & RefereeAdvisorRefereeTitlesType

Help & Info

Publishing on eDissPDF GuideTerms of ContractFAQ

Contact Us | Impressum | Cookie Consents | Data Protection Information
eDiss Office - SUB Göttingen (Central Library)
Platz der Göttinger Sieben 1
Mo - Fr 10:00 – 12:00 h


Tel.: +49 (0)551 39-27809 (general inquiries)
Tel.: +49 (0)551 39-28655 (open access/parallel publications)
ediss_AT_sub.uni-goettingen.de
[Please replace "_AT_" with the "@" sign when using our email adresses.]
Göttingen State and University Library | Göttingen University
Medicine Library (Doctoral candidates of medicine only)
Robert-Koch-Str. 40
Mon – Fri 8:00 – 24:00 h
Sat - Sun 8:00 – 22:00 h
Holidays 10:00 – 20:00 h
Tel.: +49 551 39-8395 (general inquiries)
Tel.: +49 (0)551 39-28655 (open access/parallel publications)
bbmed_AT_sub.uni-goettingen.de
[Please replace "_AT_" with the "@" sign when using our email adresses.]