| dc.contributor.advisor | Schneider, Sven Prof. Dr. | |
| dc.contributor.author | Scheibel, Isabel Christina | |
| dc.date.accessioned | 2017-01-12T10:23:21Z | |
| dc.date.available | 2017-01-12T10:23:21Z | |
| dc.date.issued | 2017-01-12 | |
| dc.identifier.uri | http://hdl.handle.net/11858/00-1735-0000-002B-7D02-8 | |
| dc.identifier.uri | http://dx.doi.org/10.53846/goediss-6070 | |
| dc.language.iso | eng | de |
| dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject.ddc | 540 | de |
| dc.title | N2 Splitting and Functionalization in the Coordination Sphere of Rhenium | de |
| dc.type | doctoralThesis | de |
| dc.contributor.referee | Schneider, Sven Prof. Dr. | |
| dc.date.examination | 2016-12-16 | |
| dc.description.abstracteng | The first example of homogeneous N2 splitting mediated by rhenium as group 7 transition metal is reported and represents rare complete scission of the N-N bond in well-defined terminal nitrido complexes. These could be alkylated with electrophiles to imido complexes. Further functionalizations transform the nitrogen containing moeity into organonitriles under recovery of the starting material. Therefore, a synthetic cycle for the transformation of N2 into nitriles comprising three reaction steps is closed. Synthesis, characterization and reactivity of all involved complexes is presented. | de |
| dc.contributor.coReferee | Meyer, Franc Prof. Dr. | |
| dc.subject.eng | N2 splitting | de |
| dc.subject.eng | rhenium | de |
| dc.subject.eng | nitrogen fixation | de |
| dc.subject.eng | small molecule activation | de |
| dc.subject.eng | acetonitrile | de |
| dc.subject.eng | pincer ligands | de |
| dc.identifier.urn | urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D02-8-3 | |
| dc.affiliation.institute | Fakultät für Chemie | de |
| dc.subject.gokfull | Chemie (PPN62138352X) | de |
| dc.identifier.ppn | 876628552 | |
| dc.creator.birthname | Klopsch | |