The Siamese-Twin Porphyrin and its Metal Complexes: Platforms for Multi-Electron Redox Chemistry

Vogel, Anastasia

dc.contributor.advisor	Meyer, Franc Prof. Dr.
dc.contributor.author	Vogel, Anastasia
dc.date.accessioned	2017-02-14T09:27:06Z
dc.date.available	2017-10-20T22:50:04Z
dc.date.issued	2017-02-14
dc.identifier.uri	http://hdl.handle.net/11858/00-1735-0000-002B-7D43-3
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-6119
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	The Siamese-Twin Porphyrin and its Metal Complexes: Platforms for Multi-Electron Redox Chemistry	de
dc.type	doctoralThesis	de
dc.contributor.referee	Meyer, Franc Prof. Dr.
dc.date.examination	2016-10-21
dc.description.abstracteng	This work comprises a redox-chemical investigation of a pyrazole-containing expanded porphyrin - the so-called Siamese-twin porphyrin. It includes synthetic organic and inorganic work and applies a series of analytical techniques. Repeated periphery-to-core fusion reactions of the ligand framework upon oxidation were studied in detail. Further, communication of the porphyrin-like hemi-macrocycles in a monopalladium(II) complex were revealed. Redox investigations and complementary calculations were performed to uncover the importance of a metalation-induced tautomerism on the electronic structure of the expanded porphyrin. Additional cooperative effects of the non-innocent ligands system and its central ion in bimetallic manganese(III) complexes were examined.	de
dc.contributor.coReferee	Diederichsen, Ulf Prof. Dr.
dc.subject.eng	expanded porphyrins	de
dc.subject.eng	oxidation	de
dc.subject.eng	macrocycles	de
dc.subject.eng	manganese	de
dc.subject.eng	palladium	de
dc.subject.eng	aromaticity	de
dc.identifier.urn	urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D43-3-1
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2017-10-20
dc.identifier.ppn	880190256

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Fakultät für Chemie (inkl. GAUSS) [701]

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