New Derivatives and Iron Complexes of the Siamese-Twin Porphyrin

Mitevski, Oliver

dc.contributor.advisor	Meyer, Franc Prof. Dr.
dc.contributor.author	Mitevski, Oliver
dc.date.accessioned	2017-02-14T09:33:28Z
dc.date.available	2017-10-17T22:50:04Z
dc.date.issued	2017-02-14
dc.identifier.uri	http://hdl.handle.net/11858/00-1735-0000-002B-7D44-1
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-6123
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	New Derivatives and Iron Complexes of the Siamese-Twin Porphyrin	de
dc.type	doctoralThesis	de
dc.contributor.referee	Meyer, Franc Prof. Dr.
dc.date.examination	2016-10-18
dc.description.abstracteng	Variation of the substitution pattern of the Siamese-twin porphyrin (STP), an expanded porphyrin incorporating two pyrazole moieties, identified a set of substituents that result in an optimized preparation of highly crystalline products. The substituents have only negligible electronic and structural influences on the free base macrocycles and their dicopper complexes. Additionally, a new class of dinuclear iron complexes of the Siamese-twin porphyrin has been established. The homo- and heterobimetallic iron complexes of the STP were structurally characterized and showed to be pure intermediate spin in EPR spectroscopy and magnetic susceptibility measurements but remarkably gave two doublets in Mößbauer spectroscopy.	de
dc.contributor.coReferee	Schneider, Sven Prof. Dr.
dc.subject.eng	Porphyrinoids	de
dc.subject.eng	Expanded Porphyrin	de
dc.subject.eng	Mößbauer	de
dc.subject.eng	Intermediate Spin	de
dc.subject.eng	Iron Complexes	de
dc.identifier.urn	urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D44-1-3
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2017-10-17
dc.identifier.ppn	880190272

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