dc.contributor.advisor | Meyer, Franc Prof. Dr. | |
dc.contributor.author | Gers-Barlag, Alexander | |
dc.date.accessioned | 2017-02-14T09:36:24Z | |
dc.date.available | 2017-11-23T23:50:08Z | |
dc.date.issued | 2017-02-14 | |
dc.identifier.uri | http://hdl.handle.net/11858/00-1735-0000-002B-7D45-0 | |
dc.identifier.uri | http://dx.doi.org/10.53846/goediss-6126 | |
dc.identifier.uri | http://dx.doi.org/10.53846/goediss-6126 | |
dc.language.iso | deu | de |
dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject.ddc | 540 | de |
dc.title | Two-in-one Pincer Type Ligands and Their Metal Complexes for Catalysis | de |
dc.type | doctoralThesis | de |
dc.title.translated | Two-in-one Pincer Type Ligands and Their Metal Complexes for Catalysis | de |
dc.contributor.referee | Meyer, Franc Prof. Dr. | |
dc.date.examination | 2016-11-24 | |
dc.description.abstracteng | The synthesis, characterization and first applications in catalysis of dinuclear metal complexes of the new Two-in-one pincer ligand scaffold are described in this work. Zinc(II) compexes were used to compare structural and electronical features of two derivatives of the ligand system. Reactivity studies revealed a broad range of reactions for a cobalt(II) complex, although detailed analysis of the reaction products was not possible so far. Furthermore, several rhodium(I) complexes have been synthesized and fully characterized. For a rhodium(I) carbonyl complex a dearomatization sequence was found for the first time in dinuclear, pyridine based pincer complexes. Mechanistic aspects of the hydrogenation of terminal phenyl acetylenes by a rhodium(I) acetonitrile complex were investigated. First results were obtained for the hydrogenation of carbon dioxide to formate salts in the presence of base. | de |
dc.contributor.coReferee | Schneider, Sven Prof. Dr. | |
dc.contributor.thirdReferee | Alcarazo, Manuel Prof. Dr. | |
dc.contributor.thirdReferee | Koszinowski, Konrad Prof. Dr. | |
dc.contributor.thirdReferee | Breder, Alexander Dr. | |
dc.contributor.thirdReferee | Demir, Selvan Dr. | |
dc.subject.eng | pincer ligands | de |
dc.subject.eng | dinuclear complexes | de |
dc.subject.eng | catalysis | de |
dc.subject.eng | metal ligand cooperativity | de |
dc.subject.eng | activation of small molecules | de |
dc.subject.eng | hydrogenation | de |
dc.identifier.urn | urn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D45-0-3 | |
dc.affiliation.institute | Fakultät für Chemie | de |
dc.subject.gokfull | Chemie (PPN62138352X) | de |
dc.description.embargoed | 2017-11-23 | |
dc.identifier.ppn | 880190299 | |