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Two-in-one Pincer Type Ligands and Their Metal Complexes for Catalysis

dc.contributor.advisorMeyer, Franc Prof. Dr.
dc.contributor.authorGers-Barlag, Alexander
dc.date.accessioned2017-02-14T09:36:24Z
dc.date.available2017-11-23T23:50:08Z
dc.date.issued2017-02-14
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-002B-7D45-0
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-6126
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-6126
dc.language.isodeude
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540de
dc.titleTwo-in-one Pincer Type Ligands and Their Metal Complexes for Catalysisde
dc.typedoctoralThesisde
dc.title.translatedTwo-in-one Pincer Type Ligands and Their Metal Complexes for Catalysisde
dc.contributor.refereeMeyer, Franc Prof. Dr.
dc.date.examination2016-11-24
dc.description.abstractengThe synthesis, characterization and first applications in catalysis of dinuclear metal complexes of the new Two-in-one pincer ligand scaffold are described in this work. Zinc(II) compexes were used to compare structural and electronical features of two derivatives of the ligand system. Reactivity studies revealed a broad range of reactions for a cobalt(II) complex, although detailed analysis of the reaction products was not possible so far. Furthermore, several rhodium(I) complexes have been synthesized and fully characterized. For a rhodium(I) carbonyl complex a dearomatization sequence was found for the first time in dinuclear, pyridine based pincer complexes. Mechanistic aspects of the hydrogenation of terminal phenyl acetylenes by a rhodium(I) acetonitrile complex were investigated. First results were obtained for the hydrogenation of carbon dioxide to formate salts in the presence of base.de
dc.contributor.coRefereeSchneider, Sven Prof. Dr.
dc.contributor.thirdRefereeAlcarazo, Manuel Prof. Dr.
dc.contributor.thirdRefereeKoszinowski, Konrad Prof. Dr.
dc.contributor.thirdRefereeBreder, Alexander Dr.
dc.contributor.thirdRefereeDemir, Selvan Dr.
dc.subject.engpincer ligandsde
dc.subject.engdinuclear complexesde
dc.subject.engcatalysisde
dc.subject.engmetal ligand cooperativityde
dc.subject.engactivation of small moleculesde
dc.subject.enghydrogenationde
dc.identifier.urnurn:nbn:de:gbv:7-11858/00-1735-0000-002B-7D45-0-3
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.description.embargoed2017-11-23
dc.identifier.ppn880190299


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