Ruthenium catalyzed C-N, C-O and C-C formation is achieved by C-H activation. access to primary aminoketones leds to synthetic synthons for different heterocycles. removable and reusability was shown first time in C-O bond formation via ruthenium catalysis. Cheapest solo oxidanr molecular di-oxygen was used to be a sacrificial oxidant in oxidative alkenylation reaction to lead fully decorated phenol derivatives.
