Ruthenium(II)-Catalyzed C-N, C-O and C-C Formations by C-H Activation

by Keshav Raghuvanshi
Doctoral thesis
Date of Examination:2017-02-06
Date of issue:2017-02-16
Advisor:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Lutz Ackermann
Referee:Prof. Dr. Konrad Koszinowski
Persistent Address: http://dx.doi.org/10.53846/goediss-6135

 

 

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Abstract

English

Ruthenium catalyzed C-N, C-O and C-C formation is achieved by C-H activation. access to primary aminoketones leds to synthetic synthons for different heterocycles. removable and reusability was shown first time in C-O bond formation via ruthenium catalysis. Cheapest solo oxidanr molecular di-oxygen was used to be a sacrificial oxidant in oxidative alkenylation reaction to lead fully decorated phenol derivatives.
Keywords: Ruthenium, C‒N, C‒O and C‒C bond, C‒H Activation, C‒H functionalization
 
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