Novel Bulky Bis(benzoxazol-2-yl)methane Ligands in s-Block Metal Coordination

Köhne, Ingo

dc.contributor.advisor	Stalke, Dietmar Prof. Dr.
dc.contributor.author	Köhne, Ingo
dc.date.accessioned	2018-05-16T08:33:40Z
dc.date.available	2018-05-16T08:33:40Z
dc.date.issued	2018-05-16
dc.identifier.uri	http://hdl.handle.net/11858/00-1735-0000-002E-E3E8-1
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-6870
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Novel Bulky Bis(benzoxazol-2-yl)methane Ligands in s-Block Metal Coordination	de
dc.type	doctoralThesis	de
dc.contributor.referee	Stalke, Dietmar Prof. Dr.
dc.date.examination	2018-04-06
dc.description.abstracteng	This thesis focusses on the preparation of bulky, NacNac-like bis(benzoxazol-2-yl)methane ligand platforms and their introduction to s-block metal coordination. Special focus is put on the synthesis of group 2 halide and -amide precursor compounds for subsequent reduction with alkali-metal reducing agents. First attempts to obtain reduced Mg(I) dimers are presented. All obtained compounds are thoroughly characterized. Moreover, the unprecedented synthesis of a solely O-coordinated organopotassium complex is discussed in detail, which exhibits a pronounced stability against hydrolysis.	de
dc.contributor.coReferee	Meyer, Franc Prof. Dr.
dc.subject.eng	metal organic chemistry	de
dc.subject.eng	bulky bis(benzoxazol-2-yl)methanes	de
dc.subject.eng	NacNac	de
dc.subject.eng	s-block metal coordination	de
dc.subject.eng	alkaline earth metals	de
dc.subject.eng	ligand engineering	de
dc.subject.eng	hydrolysis stable complexes	de
dc.identifier.urn	urn:nbn:de:gbv:7-11858/00-1735-0000-002E-E3E8-1-5
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.identifier.ppn	1022344692

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Fakultät für Chemie (inkl. GAUSS) [701]

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