New Methodologies for the Regio- and Stereoselective Electrophilic Cyanation of Alkynes

von Alejandro García Barrado
Dissertation
Datum der mündl. Prüfung:2018-11-26
Erschienen:2019-01-04
Betreuer:Prof. Dr. Manuel Alcarazo
Gutachter:Prof. Dr. Manuel Alcarazo
Gutachter:Prof. Dr. Dietmar Stalke
Gutachter:Prof. Dr. Inke Siewert
Gutachter:Dr. Alexander Breder
Gutachter:Dr. Shoubhik Das
Gutachter:Dr. Max Hansmann
Zum Verlinken/Zitieren: http://dx.doi.org/10.53846/goediss-7214

 

 

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Zusammenfassung

Englisch

The ability of sulfur imidazolium thiocyanates salts to serve as a remarkable source of cyano groups was tested, thus efficiently promoting cyanations of internal and terminal alkynes. The methods described are performed under mild conditions in a metal-free environment, making these type of salts as interesting reagents for further investigations in the field.
Keywords: Electrophilic Cyanation; Imidazolium Thiocyanates; Regioselective Cyanation of Alkynes; Stereoselective Cyanation of Alkynes; Methodology; Chlorocyanation of Alkynes; Cyanative Cyclization
 
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