Show simple item record

C–H Activation via Iridium and Rhodium Electrocatalysis and Undirected Electrochemical Fluorination

dc.contributor.advisorAckermann, Lutz Prof. Dr.
dc.contributor.authorStangier, Maximilian Daniel
dc.date.accessioned2022-06-24T10:50:16Z
dc.date.issued2022-06-24
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?ediss-11858/14123
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-9298
dc.language.isoengde
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540de
dc.titleC–H Activation via Iridium and Rhodium Electrocatalysis and Undirected Electrochemical Fluorinationde
dc.typedoctoralThesisde
dc.contributor.refereeAckermann, Lutz Prof. Dr.
dc.date.examination2022-05-24de
dc.description.abstractengIn past decades, transition metal-catalyzed C–H activation has emerged as an increasingly viable toolbox for the step- and atom economic formation of C–C and C–Het bonds. However, oxidative C–H transformations heavily rely on stoichiometric amounts of toxic and expensive metal oxidants. To overcome the drawback of sacrificial oxidants, organic electrochemistry has proven to be a powerful and sustainable alternative for transition metal-catalyzed C–H activations. Within this thesis, the concept of metallaelectrocatalysis was extended towards iridium electro-catalyzed C–H activation and the electrooxidative functionalization of formyl and alkene C–H bonds using rhodium catalysts. Furthermore, an undirected, electrochemical C(sp3)–H fluorination was developed, without the need for additional metal catalysts.de
dc.contributor.coRefereeKoszinowski, Konrad Prof. Dr.
dc.contributor.thirdRefereeStalke, Dietmar Prof. Dr.
dc.contributor.thirdRefereeJohn, Michael Dr.
dc.contributor.thirdRefereeJanßen-Müller, Daniel Dr.
dc.contributor.thirdRefereeWalker, Johannes Prof. Dr.
dc.subject.engElectrochemistryde
dc.subject.engC–H Activationde
dc.subject.engTransition Metal Catalysisde
dc.subject.engFluorinationde
dc.subject.engRhodiumde
dc.subject.engIridiumde
dc.identifier.urnurn:nbn:de:gbv:7-ediss-14123-0
dc.date.embargoed2023-05-23
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.description.embargoed2023-05-23de
dc.identifier.ppn180783140X


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record