Synthesis and Magnetic Properties of Polyimidosulfur- and Bis(benzoxazolyl)methanide-ligated Complexes

Lüert, Daniel

dc.contributor.advisor	Stalke, Dietmar Prof. Dr.
dc.contributor.author	Lüert, Daniel
dc.date.accessioned	2022-09-30T09:48:13Z
dc.date.available	2022-10-07T00:50:11Z
dc.date.issued	2022-09-30
dc.identifier.uri	http://resolver.sub.uni-goettingen.de/purl?ediss-11858/14269
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-9466
dc.language.iso	eng	de
dc.subject.ddc	540	de
dc.title	Synthesis and Magnetic Properties of Polyimidosulfur- and Bis(benzoxazolyl)methanide-ligated Complexes	de
dc.type	doctoralThesis	de
dc.contributor.referee	Stalke, Dietmar Prof. Dr.
dc.date.examination	2022-09-01	de
dc.description.abstracteng	The properties of magnetic molecules are promising centerpieces in various fields of research directed toward novel technologies, ranging from quantum computing, high-density data storage systems, and medical imaging applications, to other electron spin techniques. This work aims to generate two new approaches toward novel magnetic materials. The first focus will shine a light on the air-stable and easily tunable bis(benzoxazole-2-yl)methanide (Box) ligand family that was never employed in d- and f-metal chemistry before. Here, the goal is to establish air-stable benchmark systems of single-molecule magnets (SMMs), which allow profound studies of magneto structural correlations and qualify for high-resolution charge density experiments. Second, this thesis evaluates various alkali-metal-based triimidosulfites as versatile precursors for SMMs, demonstrating a linear coordination mode that is beneficial for fine-tuning the local anisotropy in such systems. A coordination mode with two ligands sandwiching one lanthanide ion is envisioned. Starting with the well-known lithium precursor [Li4{NtBu)3S2], the higher homologues with sodium and potassium are feasible and should provide fruitful chemistry.	de
dc.contributor.coReferee	Meyer, Franc Prof. Dr.
dc.contributor.thirdReferee	Waitz, Thomas Prof. Dr.
dc.subject.eng	single-molecule magnet	de
dc.subject.eng	triimidosulfites	de
dc.subject.eng	lanthanides	de
dc.subject.eng	dysprosium SMM	de
dc.subject.eng	Bis(benzoxazolyl)methanes	de
dc.subject.eng	transition metals	de
dc.subject.eng	magnetism	de
dc.subject.eng	cobalt SMM	de
dc.subject.eng	sulfur-nitrogen	de
dc.identifier.urn	urn:nbn:de:gbv:7-ediss-14269-4
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2022-10-07	de
dc.identifier.ppn	1817928341
dc.notes.confirmationsent	Confirmation sent 2022-09-30T10:15:01	de

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Fakultät für Chemie (inkl. GAUSS) [701]

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