Transition Metal- and Electro-Catalyzed C-H and B-H Activation for the Efficient Synthesis of Carborane Derivatives

Jei, Becky Bongsuiru

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Jei, Becky Bongsuiru
dc.date.accessioned	2023-01-12T17:24:21Z
dc.date.available	2023-01-20T00:50:09Z
dc.date.issued	2023-01-12
dc.identifier.uri	http://resolver.sub.uni-goettingen.de/purl?ediss-11858/14457
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-9654
dc.format.extent	XXX Seiten	de
dc.language.iso	eng	de
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/
dc.subject.ddc	540	de
dc.title	Transition Metal- and Electro-Catalyzed C-H and B-H Activation for the Efficient Synthesis of Carborane Derivatives	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2022-12-15	de
dc.description.abstracteng	The emergence and rapid development of transition metal-and electro-catalyzed C-H activation has proven to be a powerful tool in the assembly of complex molecular structures. in addition, the selective synthesis of carborane derivatives proceeded over the years through noble 4d metal catalysis characterized by expensive 4d metal complexes, use of stoichiometric silver salts as well as harsh reaction conditions. This has made these protocols impractical and unsustainable thereby creating a need for more sustainable protocols. The above mentioned drawbacks have been partly addressed in this dissertation through the merge of 3d transition metal catalysis and electrocatalysis for the sustainable synthesis of carborane derivatives. Notable futures of this dissertation include i) cost-efficient, earth-abundant manganese(I) catalysis for the assembly of o-carborane containing peptides ii) copper(I)-catalyzed electrooxidative cage chalcogenation of o-carboranes iii) metal-free electrochemical B-H nitrogenation of nido-carboranes for the successful synthesis of highly fluorescent BODIPY containing nido-carboranes. Furthermore, we have unraveled sustainable methods to assemble carboranes of varying functional groups and complexity. These compounds could find application in medicine as novel boron neutron capture therapy agents and in material science for optoelectronic materials.	de
dc.contributor.coReferee	Breder, Alexander Prof. Dr.
dc.contributor.thirdReferee	Tietze, Lutz Prof. Dr. Dr. h.c.
dc.contributor.thirdReferee	Stalke, Dietmar Prof. Dr.
dc.contributor.thirdReferee	Janßen-Müller, Daniel Dr.
dc.contributor.thirdReferee	John, Michael Dr.
dc.subject.ger	sustainable catalysis, C-H/B-H activation, Carborane derivatives	de
dc.subject.eng	sustainable catalysis, C-H/B-H activation, Carborane derivatives	de
dc.identifier.urn	urn:nbn:de:gbv:7-ediss-14457-5
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2023-01-20	de
dc.identifier.ppn	1831019280
dc.notes.confirmationsent	Confirmation sent 2023-01-13T06:15:01	de

Dateien

Name:Thesis 04.01.2023.pdf

Größe:34.71Mb

Format:PDF

Beschreibung:PhD Dissertation

Öffnen

Name:: Thesis 04.01.2023.pdf
Größe:: 34.71Mb
Format:: PDF
Beschreibung:: PhD Dissertation

Öffnen

Das Dokument erscheint in:

Fakultät für Chemie (inkl. GAUSS) [700]

Zur Kurzanzeige