| dc.contributor.advisor | Meyer, Franc Prof. Dr. | |
| dc.contributor.author | Hu, Lanxia | |
| dc.date.accessioned | 2023-03-20T17:16:08Z | |
| dc.date.available | 2024-02-20T00:50:09Z | |
| dc.date.issued | 2023-03-20 | |
| dc.identifier.uri | http://resolver.sub.uni-goettingen.de/purl?ediss-11858/14587 | |
| dc.identifier.uri | http://dx.doi.org/10.53846/goediss-9794 | |
| dc.format.extent | XXX Seiten | de |
| dc.language.iso | eng | de |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.subject.ddc | 540 | de |
| dc.title | New Synthetic Analogues for Biological Fe/S Clusters | de |
| dc.type | doctoralThesis | de |
| dc.contributor.referee | Siewert, Inke Prof. Dr. | |
| dc.date.examination | 2023-02-21 | de |
| dc.description.abstracteng | Iron-sulfur (Fe/S) clusters are omnipresent and are essential components in virtually all life forms due to their versatile structures and functions. Biological systems extensively employ Fe/S clusters, especially with rhombic [2Fe-2S] and cubane-type [4Fe-4S] cores for electron transfer, catalysis, etc. Studies on synthetic Fe/S complexes have provided deeper insight into their structures and functions. By comparison, asymmetrical Fe/S clusters are not well investigated. This thesis mainly focuses on establishing novel synthetic analogues for biological asymmetrical [2Fe-2S] and [4Fe-4S] clusters. A series novel of [2Fe-2S] and [4Fe-4S] clusters were synthesized and fully characterized, and their redox properties were investigated. The detailed research of these clusters deepened our understanding of asymmetrical Fe/S clusters. | de |
| dc.contributor.coReferee | Vondung, Lisa Prof. Dr. | |
| dc.contributor.thirdReferee | Krawczuk, Anna Prof. Dr. | |
| dc.contributor.thirdReferee | John, Michael Dr. | |
| dc.contributor.thirdReferee | Frauendorf, Holm Dr. | |
| dc.subject.eng | [2Fe-2S] clusters, [4Fe-4S] clusters, asymmetrical Fe/S clusters | de |
| dc.subject.eng | [4Fe-4S] clusters | |
| dc.subject.eng | asymmetrical Fe/S clusters | |
| dc.identifier.urn | urn:nbn:de:gbv:7-ediss-14587-6 | |
| dc.affiliation.institute | Fakultät für Chemie | de |
| dc.subject.gokfull | Chemie (PPN62138352X) | de |
| dc.description.embargoed | 2024-02-20 | de |
| dc.identifier.ppn | 1839626585 | |
| dc.notes.confirmationsent | Confirmation sent 2023-03-21T06:15:01 | de |