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New Synthetic Analogues for Biological Fe/S Clusters

dc.contributor.advisorMeyer, Franc Prof. Dr.
dc.contributor.authorHu, Lanxia
dc.date.accessioned2023-03-20T17:16:08Z
dc.date.available2024-02-20T00:50:09Z
dc.date.issued2023-03-20
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?ediss-11858/14587
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-9794
dc.format.extentXXX Seitende
dc.language.isoengde
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540de
dc.titleNew Synthetic Analogues for Biological Fe/S Clustersde
dc.typedoctoralThesisde
dc.contributor.refereeSiewert, Inke Prof. Dr.
dc.date.examination2023-02-21de
dc.description.abstractengIron-sulfur (Fe/S) clusters are omnipresent and are essential components in virtually all life forms due to their versatile structures and functions. Biological systems extensively employ Fe/S clusters, especially with rhombic [2Fe-2S] and cubane-type [4Fe-4S] cores for electron transfer, catalysis, etc. Studies on synthetic Fe/S complexes have provided deeper insight into their structures and functions. By comparison, asymmetrical Fe/S clusters are not well investigated. This thesis mainly focuses on establishing novel synthetic analogues for biological asymmetrical [2Fe-2S] and [4Fe-4S] clusters. A series novel of [2Fe-2S] and [4Fe-4S] clusters were synthesized and fully characterized, and their redox properties were investigated. The detailed research of these clusters deepened our understanding of asymmetrical Fe/S clusters.de
dc.contributor.coRefereeVondung, Lisa Prof. Dr.
dc.contributor.thirdRefereeKrawczuk, Anna Prof. Dr.
dc.contributor.thirdRefereeJohn, Michael Dr.
dc.contributor.thirdRefereeFrauendorf, Holm Dr.
dc.subject.eng[2Fe-2S] clusters, [4Fe-4S] clusters, asymmetrical Fe/S clustersde
dc.subject.eng[4Fe-4S] clusters
dc.subject.engasymmetrical Fe/S clusters
dc.identifier.urnurn:nbn:de:gbv:7-ediss-14587-6
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.description.embargoed2024-02-20de
dc.identifier.ppn1839626585
dc.notes.confirmationsentConfirmation sent 2023-03-21T06:15:01de


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