Sustainable Ruthenium- and Rhodium-Catalyzed C−H Activations with Photochemistry and Electrochemistry

Zangarelli, Agnese

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Zangarelli, Agnese
dc.date.accessioned	2024-03-18T11:55:44Z
dc.date.available	2024-03-25T00:50:09Z
dc.date.issued	2024-03-18
dc.identifier.uri	http://resolver.sub.uni-goettingen.de/purl?ediss-11858/15171
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-10400
dc.format.extent	275	de
dc.language.iso	eng	de
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/
dc.subject.ddc	540	de
dc.title	Sustainable Ruthenium- and Rhodium-Catalyzed C−H Activations with Photochemistry and Electrochemistry	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2024-02-29	de
dc.description.abstracteng	Cross-coupling chemistry stands out as a fundamental tool in synthetic organic chemistry for forging C‒C and C‒Het bonds. However, the necessity for substrate prefunctionalization imposes significant sustainability challenges on these transformations. In contrast, advancements in transition metal-catalyzed direct functionalization of ubiquitous C‒H bonds present a more sustainable avenue for constructing complex molecular structures. Despite the pivotal contributions of C–H activation, also driven by key principles like atom- and step-economy, this approach has inherent limitations. To overcome these, innovative mechanistic pathways integrating renewable energy sources in electrocatalysis and photocatalysis are pursued to address issues related to hazardous chemical oxidants and harsh reaction conditions. Additionally, with the aim of synthetic utility and applicability in drug discovery and medicinal chemistry, late-stage C–H functionalization can be implemented with the promise for simplifying reaction pathways and diversifying product outputs. These themes constitute the central investigative focus of this thesis.	de
dc.contributor.coReferee	Koszinowski, Konrad Prof. Dr.
dc.contributor.thirdReferee	Meyer, Franc Prof. Dr.
dc.contributor.thirdReferee	Tietze, Lutz Prof. Dr. Dr.
dc.contributor.thirdReferee	Frauendorf, Holm Dr.
dc.contributor.thirdReferee	Janßen-Müller, Daniel Dr.
dc.subject.eng	Catalysis	de
dc.subject.eng	C–H Activation	de
dc.subject.eng	C–H Functionalization	de
dc.subject.eng	Sustainability	de
dc.subject.eng	Photochemistry	de
dc.subject.eng	Electrochemistry	de
dc.subject.eng	Late-Stage Functionalization	de
dc.identifier.urn	urn:nbn:de:gbv:7-ediss-15171-2
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2024-03-25	de
dc.identifier.ppn	1883881722
dc.notes.confirmationsent	Confirmation sent 2024-05-02T10:15:01	de

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