Pallada-Electrocatalyzed Non-Directed C–H Alkenylation and Double C–H Arylation

Lin, Zhipeng

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Lin, Zhipeng
dc.date.accessioned	2024-12-19T12:21:04Z
dc.date.available	2024-12-26T00:50:10Z
dc.date.issued	2024-12-19
dc.identifier.uri	http://resolver.sub.uni-goettingen.de/purl?ediss-11858/15704
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-10956
dc.format.extent	484	de
dc.language.iso	eng	de
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/
dc.subject.ddc	540	de
dc.title	Pallada-Electrocatalyzed Non-Directed C–H Alkenylation and Double C–H Arylation	de
dc.type	doctoralThesis	de
dc.contributor.referee	Jooß, Christian Prof. Dr.
dc.date.examination	2024-07-10	de
dc.description.abstracteng	The merger of electrooxidation and transition metal-catalyzed C–H activation has emerged as an increasingly viable platform in molecular syntheses that can avoid stoichiometric chemical redox agents and circuitous functional group operations. Despite significant progress, these electrochemical C−H activations generally require directing groups, of which the installation and removal call for additional synthesis steps, leading to undesired waste with reduced step and atom economy. In his thesis, we present palladium-electrochemical C−H olefinations of simple arenes devoid of exogenous directing groups. The robust electrocatalysis protocol proved amenable to a wide range of both electron-rich and electron-deficient arenes under exceedingly mild reaction conditions, avoiding chemical oxidants. This study points to an interesting approach of two electrochemical transformations for the success of outstanding levels of position-selectivities in direct olefinations of electron-rich anisoles. Furthermore, late-stage	de
dc.contributor.coReferee	Tietze, Lutz Prof. Dr. Dr. h.c.
dc.contributor.thirdReferee	Frauendorf, Holm Dr.
dc.contributor.thirdReferee	Simeth, Nadja Jun.-Prof. Dr.
dc.contributor.thirdReferee	Janßen-Müller, Daniel Dr.
dc.subject.eng	directing group free	de
dc.subject.eng	C-H Activation	de
dc.subject.eng	palladium	de
dc.subject.eng	electrochemistry	de
dc.subject.eng	cross dehydrogenative coupling	de
dc.subject.eng	arylation	de
dc.subject.eng	alkenylation	de
dc.identifier.urn	urn:nbn:de:gbv:7-ediss-15704-2
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2024-12-26	de
dc.identifier.ppn	1914849973
dc.notes.confirmationsent	Confirmation sent 2024-12-19T12:45:01	de

Files in this item

Name:dissertation_Zhipeng Lin.pdf

Size:29.17Mb

Format:PDF

View/Open

Name:: dissertation_Zhipeng Lin.pdf
Size:: 29.17Mb
Format:: PDF

View/Open

This item appears in the following Collection(s)

Fakultät für Chemie (inkl. GAUSS) [726]

Show simple item record