Browsing Fakultät für Chemie (inkl. GAUSS) by Advisor & Referee "Schneider, Sven Prof. Dr."
Now showing items 1-20 of 47
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C-H Bond Activation by Iridium(III) and Iridium(IV) Oxo Complexes
(2025-06-11)C−H activation by two isostructural, terminal iridium(III) and iridium(IV) oxo complexes is compared. While the driving forces for hydrogen abstraction are almost identical due to compensating contributions from H+ and e− ... -
Preorganization within a pyrazolato-bridged bis-β-diketiminato dinickel frame as a key tool to access terminal sulfides and synergistically stabilized intermediates for acetyl-CoA synthase mimetic thioester formation
(2025-05-21)Bimetallic complexes are frequently employed in natural enzymes and in applications such as imaging, targeting, and catalysis, in order to exploit the synergy between two metal centers or to combine different functionali ... -
Transient Triplet Metallopnictinidenes
(2025-04-30)Nitrenes (N–R) are subvalent key intermediates in organic synthesis and have been extensively studied. The heavier pnictinidene analogues have also attracted great interest, but comprehensive investigations that systematically ... -
Reductive Small Molecule Transformations with Pyrazolate-Based Bimetallic Complexes
(2025-01-23)The activation of small molecules (NO, O2, CO, CO2, N2, etc.) is important in a multitude of fields such as biology, medicine and industrial catalysis. Many synthetic catalysts were inspired by the active sites of ... -
Electron Rich Metallo Nitrene Complexes For Nitrogen Transfer
(2025-01-10)The advent of C–N bond formation by catalytic C–H amination had a huge impact on the synthesis of nitrogen-containing compounds, in academia as well as industry. In contrast to nitrogen-group transfer, complementary ... -
Proton-Coupled Electron Transfer Studies on a Series of Osmium and Iridium Hydride Complexes
(2024-11-15)Due to the important role of transition metal hydrides in organometallic catalysis, their properties and reactivity have been thoroughly investigated and reviewed. Considering their importance, substantial efforts were ... -
Femtosecond spectroscopy of charge-transfer dynamics in self-assembled Pd(II) based donor-acceptor/host-guest cages and heterobinuclear alkyne-bridged W(II)-Ru(II) and W(II)-Ir(III) complexes
(2024-04-11)Using femtosecond UV/vis-pump-UV/vis-probe and -midIR-probe absorption spectroscopy the charge-transfer dynamics of self-assembling donor-acceptor Pd(II) coordination cages and heterobinuclear alkyne-bridged W(II)-Ru(II) ... -
Cobalt-Catalyzed Olefin Hydrogenation
(2023-08-04)This thesis describes the synthesis and isolation of the cobalt complexes, using PNP-pincer ligand system with tert-butyl substituents. The neutral and cationic cobalt hydrides were further probed in olefin hydrogenation ... -
Rhenium Mediated Formation of N-Containing Organic Compounds by Nitride Transfer
(2023-01-26)N-containing organic compounds occur in all the organisms, such as in the form of amino acids (and thus proteins), nucleic acids (DNA and RNA), and in the form of energy transfer molecule adenosine triphosphate. The human ... -
Tuning the donor properties of bipyridyl-substituted phosphines by metal ion encapsulation & Photocatalytic synthesis of 6H-benzo[c]chromenes from S-aryl sulfonium salts
(2022-11-09)This work is divided into two parts. The first part introduces a novel approach for the synthesis of cationic phosphine ligands by metal ion encapsulation. In this context, multidentate heterophosphines encapsulate a ... -
Ramanspektroskopische Untersuchung der Esterfaltung in Überschallexpansionen, Oder: Wie man bei der Suche nach der Haarnadel im Esterhaufen fünf auf einmal findet
(2022-06-29)The conformational preference of linear alkyl chains with an ester group in the center was investigated using Raman spectroscopy in supersonic expansions. Like alkanes, short esters prefer a stretched conformation, but ... -
Electrochemical Dinitrogen Splitting and Nitride Transfer to Nitric Oxide with Rhenium Pincer Complexes
(2022-04-26)The Haber-Bosch process for the synthesis of ammonia from nitrogen and hydrogen consumes large amounts of energy and additionally relies on fossil feedstocks for the production of hydrogen. Alternative approaches for the ... -
Application of Asymmetric Gold-Catalyzed Hydroarylation in the Enantioselective Synthesis of Helicenes
(2022-04-07)A novel family of electron deficient, α-cationic ligands was synthesized, combining a chiral TADDOL-backbone with an electron withdrawing 1,2,3-triazolium moiety. Coordination to Au(I) gave the respective catalysts. Both ... -
Late-Stage Peptide Functionalization by Transition Metal-free and Palladium-Catalyzed C–H Arylations
(2022-03-31)The focus of this thesis was set on the late-stage modification of peptides through transition metal-free and palladium-catalyzed C–H arylations. At first, the scope of the transition metal-free C2-arylation of the ... -
N2 Fixation by Chromium and Rhenium PNP Pincer Complexes
(2022-03-16)This thesis focusses on the activation and functionalization of atmospheric dinitrogen by chromium and rhenium based transition metal complexes. The electronic structure of dinitrogen bridged key species is discussed based ... -
Structure-Property Correlations in Luminescent Anthracene Derivatives
(2022-02-17)This thesis aims to investigate the structure-property relationship of luminescent Anthracene derivatives. For this purpose, the Anthracene fluorophore was functionalized in various positions and with different substituents. ... -
Electrochemical N2-splitting and functionalisation in the coordination sphere of Rhenium
(2021-07-13)This thesis describes the exchange of stoichiometric, wasteful chemical redox-reagents with electrochemical activation methods within a rhenium-mediated N2-splitting and functionalisation cycle. After establishing ... -
Small Molecule Activation with Dinuclear Cobalt Complexes based on the Two-In-One Pincer Ligands
(2021-06-24)Dinuclear complexes based on this two-in-one pincer ligand scaffold have exhibited fascinating magnetic properties and promise high reactivity in catalysis and small molecule activation. In this thesis, the main objective ... -
Transformations of Energy-Related Small Molecules at Dinuclear Complexes
(2021-02-05)The urgent need for the development of carbon-neutral energy conversion schemes has inspired chemists worldwide to investigate catalytic water splitting using sunlight as the energy source. A key component for the preparation ... -
Proton Coupled Electron Transfer at Heavy Metal Sites
(2021-01-14)Terminal, late transition metal, oxo complexes are pivotal intermediates in oxygenation chemistry. This thesis describes the synthesis and full characterisation of an open-shell terminal oxo complex of iridium from the ...