Browsing Fakultät für Chemie (inkl. GAUSS) by Referee "Zeuch, Thomas PD Dr."
Now showing items 1-14 of 14
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Anwendungsbezogene Weiterentwicklung der abbildenden Ellipsometrie
(2017-10-10)Since the work of Geim of graphene as the first 2D material, application and rese- arch of 2D materials is the main booming branch this decade. Overall the imaging techniques like RAMAN Imaging, AFM and optical microscopy ... -
Biomimetic Polymer Systems via RAFT Polymerization - Routes to High-Performance Materials
(2016-12-13)Nature provides numerous examples of structural materials with outstanding mechanical properties. An especially intriguing material is spider dragline silk that outmatches man-made high-performance fibers such as Kevlar ... -
Diagonal and Off-Diagonal Anharmonicity in Hydrogen-Bonded Systems
(2016-05-11)The stretching wavenumber of a functional group exhibits a characteristic shift towards lower energies when serving as a hydrogen bond donor. This well-known effect constitutes an important tool for the study of such ... -
Electron Emission from Metastable Carbon Monoxide Molecules at Adsorbate Covered Au(111) Surfaces
(2015-07-09)Understanding the fundamentals of energy transfer between molecules and surfaces is of profound importance in modern chemistry. Here, I investigate an important energy transfer process, electron ... -
Funktionelle Polymere mittels kontrollierter Polymerisationstechniken: Von der Massenspektrometrie endfunktionalisierter Polymere und den mechanischen Eigenschaften photovernetzbarer Blockcopolymere
(2019-02-06)In this thesis polymers were functionalized with terminal ammonium groups leading to new fields of their application. Their analysis by mass spectrometry was optimized or became generally accessible. In addition, reversibly ... -
Generation of H-Atom Pulses and Associative Desorption of Hydrogen Isotopologues from Metal Surfaces
(2018-03-28)Part I of this work introduces a technique for the generation of H-atom pulses with unprecedented time resolution. In part II an extensive study of the associative desorption reaction of hydrogen isotopologues from metal ... -
Größenselektive Untersuchungen zur Kristallisation und Struktur von Wasserclustern
(2015-05-19)Vibrational spectra of neutral Na(H2O)n clusters in the OH stretching region (2800 – 3800 cm-1) were measured size selectively up to n=575±25. The IR action spectra were obtained by exploiting the increase to the photoionization ... -
Kinetik der radikalischen Polymerisation von Monomeren mit mesogener Seitengruppe in isotroper und anisotroper Lösung
(2018-03-19)This work targets the radical polymerization of reactive mesogens in isotropic and anisotropic solution. Kinetic coefficients were determined via pulse-laser polymerization in conjunction with size-exclusion chromatography ... -
Orientation-dependent energy transfer in gas-surface collisions: Scattering of vibrationally excited nitric oxide from Au(111)
(2015-07-14)The work in my thesis is a contribution to the field of chemical dynamics at surfaces. In this field we seek to develop a detailed microscopic understanding of chemical events taking place on surfaces. Progress in ...
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Photoionization and vibrational spectroscopy of sodium doped water clusters
(2019-04-15)In this work sodium doped water clusters are studied by means of photoionization reflectron time-of-flight mass spectrometry. Addition of an laser pulse of infrared radiation to the photoionization laser pulse sequence ... -
Radical Polymerization Kinetics of Non-Ionized and Fully-Ionized Monomers Studied by Pulsed-Laser EPR
(2016-06-29)The radical polymerization kinetics of non-ionized and fully-ionized monomers in organic and aqueous solution was investigated by SP–PLP–EPR, i.e., highly time-resolved single-pulse–pulsed-laser–polymerization (SP–PLP) in ... -
Schwingungsspektroskopie nah- und überkritischer Lösungsmittel
(2013-07-29)Expansions of compressed fluids find wide application. Here, they are characterized via vibrational spectroscopy. The focus is on the phase state of particles emerging from flash atomization of compressed liquids. As a ... -
Strukturdynamik wasserhaltiger Aggregate in Überschallexpansionen
(2014-07-08)Isolated molecular clusters can be investigated by Fourier transform infrared spectroscopy of supersonic expansions. It is shown how multi slit nozzles of different geometries can be used both for the elucidation of the ... -
Untersuchungen zum Einfluss von London-Dispersionswechselwirkungen auf die Molekülaggregation
(2015-06-24)The energetics and dynamics of intermolecular interactions are at the core of fundamental research in physical chemistry. Noncovalent intermolecular interactions are studied on all scales of molecular size, ranging from ...