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Development of Photo-Induced C–H Activation by Copper and Ruthenium Catalysis

dc.contributor.advisorAckermann, Lutz Prof. Dr.
dc.contributor.authorKoeller, Julian
dc.date.accessioned2019-11-08T09:10:21Z
dc.date.available2019-11-08T09:10:21Z
dc.date.issued2019-11-08
dc.identifier.urihttp://hdl.handle.net/21.11130/00-1735-0000-0005-129A-9
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-7730
dc.language.isoengde
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540de
dc.titleDevelopment of Photo-Induced C–H Activation by Copper and Ruthenium Catalysisde
dc.typedoctoralThesisde
dc.contributor.refereeAckermann, Lutz Prof. Dr.
dc.date.examination2019-10-29
dc.description.abstractengWithin recent decades, transition metal-catalyzed C–H activation has become a valuable and versatile tool for organic synthesis. As C–H bonds are ubiquitous in organic molecules, the direct site-selective functionalization of C–H bonds can avoid pre-functionalization and thereby enhances the step- and atom economy of the synthesis. This thesis illustrates the use of earth-abundant and cost-effective copper catalysts for the facile C–H chalcogenation of indolines and indoles. By merging transition metal catalysis with photocatalysis, inexpensive copper catalysts could also be employed for the C–H arylation of azoles at ambient temperature. This concept of photo-induced C–H activation was also applied to the meta-selective ruthenium-catalyzed C–H alkylation.de
dc.contributor.coRefereeKoszinowski, Konrad Prof. Dr.
dc.contributor.thirdRefereeTietze, Lutz Prof. Dr. Dr.
dc.contributor.thirdRefereeStalke, Dietmar Prof. Dr.
dc.contributor.thirdRefereeFrauendorf, Holm Dr.
dc.contributor.thirdRefereeJohn, Michael Dr.
dc.subject.engarylationde
dc.subject.engrutheniumde
dc.subject.engphotocatalysisde
dc.subject.engmeta-selective alkylationde
dc.subject.engchalcogenationde
dc.subject.engC–H activationde
dc.subject.engcopperde
dc.subject.engtransition metal catalysisde
dc.subject.engphoto-inducedde
dc.identifier.urnurn:nbn:de:gbv:7-21.11130/00-1735-0000-0005-129A-9-4
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.identifier.ppn1681544016


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