| dc.contributor.advisor | Ackermann, Lutz Prof. Dr. | |
| dc.contributor.author | Zhu, Cuiju | |
| dc.date.accessioned | 2020-01-20T10:01:14Z | |
| dc.date.available | 2020-01-20T10:01:14Z | |
| dc.date.issued | 2020-01-20 | |
| dc.identifier.uri | http://hdl.handle.net/21.11130/00-1735-0000-0005-12F3-4 | |
| dc.identifier.uri | http://dx.doi.org/10.53846/goediss-7807 | |
| dc.language.iso | eng | de |
| dc.publisher | Niedersächsische Staats- und Universitätsbibliothek Göttingen | de |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject.ddc | 540 | de |
| dc.title | Sustainable Synthesis by 3d Transition Metal Electro-Catalyzed C─H Activation | de |
| dc.type | doctoralThesis | de |
| dc.contributor.referee | Ackermann, Lutz Prof. Dr. | |
| dc.date.examination | 2019-12-10 | |
| dc.description.abstracteng | During the last years, new opportunities are represented by the development of 3d transition metal-catalyzed C–H activation, with possible benefits due to the significantly lower toxicity, high natural abundance and cost-effective nature of the employed metal catalysts. Within this thesis, two complexity-increasing domino reactions catalyzed by Cobalt and Manganese catalysts were developed. Furthermore, the first sustainable manganese(II/III/I)-catalyzed C–H arylations in continuous flow technology were achieved. Additionally, toxic and cost-intensive dihalide oxidants were for the first time replaced by electricity as a green and sustainable oxidant, allowing for versatile iron- and manganese-catalyzed C–H activations. | de |
| dc.contributor.coReferee | Breder, Alexander Prof. Dr. | |
| dc.contributor.thirdReferee | Koszinowski, Konrad Prof. Dr. | |
| dc.contributor.thirdReferee | Alcarazo, Manuel Prof. Dr. | |
| dc.contributor.thirdReferee | Frauendorf, Holm Dr. | |
| dc.contributor.thirdReferee | John, Michael Dr. | |
| dc.subject.eng | 3d Transition Metal; Cobalt; Manganese; Domino Reaction; Continuous Flow; Electrochemistry. | de |
| dc.identifier.urn | urn:nbn:de:gbv:7-21.11130/00-1735-0000-0005-12F3-4-4 | |
| dc.affiliation.institute | Fakultät für Chemie | de |
| dc.subject.gokfull | Chemie (PPN62138352X) | de |
| dc.identifier.ppn | 1687917671 | |