Iron-Catalyzed C–H/N–H Activations for Annulation of Allenes, Alkynes, and Bicyclopropylidenes

Mo, Jiayu

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Mo, Jiayu
dc.date.accessioned	2020-11-16T14:00:46Z
dc.date.available	2020-11-16T14:00:46Z
dc.date.issued	2020-11-16
dc.identifier.uri	http://hdl.handle.net/21.11130/00-1735-0000-0005-14F0-5
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-8299
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Iron-Catalyzed C–H/N–H Activations for Annulation of Allenes, Alkynes, and Bicyclopropylidenes	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2020-10-26
dc.description.abstracteng	Iron-catalyzed C–H/N–H activations for the annulation of allenes, alkynes, and bicyclopropylidenes were realized by using a customizable clickable triazole amide under mild reaction conditions. The powerful iron catalysis occurred under external‐oxidant‐free conditions even at room temperature. A unifying mechanistic approach combining experiments, Mössbauer spectroscopy was employed to delineate the reaction mechanisms. The synthetic utility of the iron‐catalyzed oxidant‐free C−H functionalizations was illustrated by the traceless removal of the modular TAH/TAM group in a user‐friendly fashion.	de
dc.contributor.coReferee	Breder, Alexander Dr.
dc.contributor.thirdReferee	Tietze, Lutz Prof. Dr. Dr.
dc.contributor.thirdReferee	Bennati, Marina Prof. Dr.
dc.contributor.thirdReferee	Mata, Ricardo Prof. Dr.
dc.contributor.thirdReferee	Walker, Johannes C. L. Prof. Dr.
dc.subject.eng	Iron	de
dc.subject.eng	C–H Activation	de
dc.subject.eng	Allenes	de
dc.subject.eng	Bicyclopropylidenes	de
dc.subject.eng	alkynes	de
dc.subject.eng	redox-neutral reactions	de
dc.identifier.urn	urn:nbn:de:gbv:7-21.11130/00-1735-0000-0005-14F0-5-4
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.identifier.ppn	1738860612

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Name:: Disertation Jiayu Mo-Final-edi ...
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Beschreibung:: Iron-Catalyzed C–H/N–H Activations ...

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Fakultät für Chemie (inkl. GAUSS) [701]

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