Selective C–H Activation by Ruthenium(II) Carboxylate and Nickelaelectro-Catalysis

Zhang, Shoukun

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Zhang, Shoukun
dc.date.accessioned	2021-01-28T08:08:43Z
dc.date.available	2021-01-28T08:08:43Z
dc.date.issued	2021-01-28
dc.identifier.uri	http://hdl.handle.net/21.11130/00-1735-0000-0005-155B-E
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-8417
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Selective C–H Activation by Ruthenium(II) Carboxylate and Nickelaelectro-Catalysis	de
dc.type	doctoralThesis	de
dc.contributor.referee	Das, Shoubhik Prof. Dr.
dc.date.examination	2021-01-11
dc.description.abstracteng	This doctoral thesis was divided into two main parts. In the first part, ruthenium(II)-catalyzed ortho-C–H alkynylations of diverse benzoic acids were achieved for the synthesis of aromatic alkynes. And meta-C–H activations, including mono- or difluoromethylation and alkylation through the σ-activation of the cyclometallated intermediate were also efficiently developed by ruthenium catalysis. In the second part, the first nickela-electrochemical C–H activation, including C–H amination, challenging secondary alkoxylation and phosphorylation in a dehydrogenative manner employing green and cheap electricity as the oxidant, providing an expedient approach to arylamines, aryl ethers and arylphosphonates. Detailed mechanistic studies including the isolation of catalytically relevant nickel(III) complex, cyclovoltammetry, and computation provided strong support for an oxidation-induced reductive elimination at nickel(III).	de
dc.contributor.coReferee	Alcarazo, Manuel Prof. Dr.
dc.contributor.thirdReferee	Stalke, Dietmar Prof. Dr.
dc.contributor.thirdReferee	Walker, Johannes C. L. Jun.-prof. Dr.
dc.contributor.thirdReferee	John, Michael Dr.
dc.subject.eng	meta-C–H difluomethylation or monofluomethylation	de
dc.subject.eng	C–H Activation	de
dc.subject.eng	C–H Amination	de
dc.subject.eng	C–H Alkoxylation	de
dc.subject.eng	C–H Phosphorylation	de
dc.subject.eng	ortho-C–H alkynylation	de
dc.subject.eng	Nickel	de
dc.subject.eng	Ruthenium	de
dc.subject.eng	Electrochemistry	de
dc.subject.eng	Electrocatalysis	de
dc.identifier.urn	urn:nbn:de:gbv:7-21.11130/00-1735-0000-0005-155B-E-6
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.identifier.ppn	174598061X

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Name:PhD dissertation_Shoukun Zhang.pdf

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Name:: PhD dissertation_Shoukun Zhang.pdf
Größe:: 34.16Mb
Format:: PDF
Beschreibung:: meta- or ortho- C–H Activation ...

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Fakultät für Chemie (inkl. GAUSS) [701]

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