Resource-Economical Synthesis by Selective Metal-Catalyzed C–H Activations

Dhawa, Uttam

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Dhawa, Uttam
dc.date.accessioned	2021-04-30T10:59:49Z
dc.date.available	2021-05-07T00:50:14Z
dc.date.issued	2021-04-30
dc.identifier.uri	http://hdl.handle.net/21.11130/00-1735-0000-0008-580E-7
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-8578
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Resource-Economical Synthesis by Selective Metal-Catalyzed C–H Activations	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2021-04-15
dc.description.abstracteng	The advent of new synthetic strategies has enriched the synthetic organic chemistry to access molecules with tremendous complexity. In this context, transition metal-catalyzed C−H activation has emerged as a powerful tool for highly step- and atom- economical synthesis that avoids laborious prefunctionalizations of starting materials. First part of the thesis was focused on removable directing group assisted challenging C–F/C–H functionalization using versatile manganese(I) and ruthenium(II) catalysis manifold. As with fluorinated scaffolds, chiral molecules represent a class of highly desirable building blocks. Thus, the next part of the thesis focused on the development of sustainable enantioselective transformations using cost-effective transition metals. Similarly, metallaelectrocatalysis provides excellent resource economy for sustainable organic synthesis. A major portion of the thesis was focused on addressing improved sustainability and resource-economy for the activation of inert C–H bonds. The prime focus of the thesis was the development of cost-effective and environmentally-benign metal-catalyzed selective C−H activation reactions with olefins and alkynes with a major emphasis on the identification of resource-economical conditions. In addition, a considerable focus has been placed on the mechanistic understandings of these C−H activations.	de
dc.contributor.coReferee	Alcarazo, Manuel Prof. Dr.
dc.contributor.thirdReferee	Tietze, Lutz Prof. Dr. Dr.
dc.contributor.thirdReferee	Mata, Ricardo Prof. Dr.
dc.contributor.thirdReferee	John, Michael Dr.
dc.contributor.thirdReferee	Janßen-Müller, Daniel Dr.
dc.subject.eng	Resource-Economy	de
dc.subject.eng	Chiral Acid	de
dc.subject.eng	C–H Activation	de
dc.subject.eng	Asymmetric Catalysis	de
dc.subject.eng	Electrosynthesis	de
dc.subject.eng	Homogenous Catalysis	de
dc.subject.eng	Transition Metal Catalysis	de
dc.subject.eng	C–F Activation	de
dc.identifier.urn	urn:nbn:de:gbv:7-21.11130/00-1735-0000-0008-580E-7-3
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2021-05-07
dc.identifier.ppn	1756852952

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