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Electrochemical N2-splitting and functionalisation in the coordination sphere of Rhenium

dc.contributor.advisorSchneider, Sven Prof. Dr.
dc.contributor.authorvan Alten, Richt Sieteke
dc.date.accessioned2021-07-13T09:58:19Z
dc.date.available2021-07-20T00:50:06Z
dc.date.issued2021-07-13
dc.identifier.urihttp://hdl.handle.net/21.11130/00-1735-0000-0008-58A6-A
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-8727
dc.identifier.urihttp://dx.doi.org/10.53846/goediss-8727
dc.language.isoengde
dc.publisherNiedersächsische Staats- und Universitätsbibliothek Göttingende
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540de
dc.titleElectrochemical N2-splitting and functionalisation in the coordination sphere of Rheniumde
dc.typedoctoralThesisde
dc.contributor.refereeSchneider, Sven Prof. Dr.
dc.date.examination2021-06-21
dc.description.abstractengThis thesis describes the exchange of stoichiometric, wasteful chemical redox-reagents with electrochemical activation methods within a rhenium-mediated N2-splitting and functionalisation cycle. After establishing electrochemical N2 splitting into a molecular defined nitride complex, a mechanistic pathway was proposed for this reaction based on extensive spectroscopic and electrochemical studies. Subsequently, two series of different rhenium complexes with modified ancillary ligands were synthesised to substantiate and expand our mechanistic understanding and to formulate design parameters for the development of future electrocatalysts. Furthermore, the oxidative functionalization of the nitrides towards acetonitrile was transformed towards electrochemical activation and extended to an additional platform. Hereby, a stoichiometric N2 splitting and functionalization cycle was electrified.de
dc.contributor.coRefereeSiewert, Inke Prof. Dr.
dc.subject.engElectrochemistryde
dc.subject.engOrganometallic chemistryde
dc.subject.engN2 splitting and functionalisationde
dc.subject.engRheniumde
dc.subject.engSpectroscopyde
dc.subject.engElectrolysisde
dc.subject.engstructure-reactivity relationsshipsde
dc.identifier.urnurn:nbn:de:gbv:7-21.11130/00-1735-0000-0008-58A6-A-6
dc.affiliation.instituteFakultät für Chemiede
dc.subject.gokfullChemie  (PPN62138352X)de
dc.description.embargoed2021-07-20
dc.identifier.ppn1762841002


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