Earth-Abundant Transition Metal-Catalyzed Electro-Reductive Cross-Electrophile Coupling Reactions and C–H Activation by Cobaltaelectro-Catalysis

Ang, Nate Woon Jie

dc.contributor.advisor	Ackermann, Lutz Prof. Dr.
dc.contributor.author	Ang, Nate Woon Jie
dc.date.accessioned	2021-12-13T12:40:35Z
dc.date.available	2021-12-20T00:50:04Z
dc.date.issued	2021-12-13
dc.identifier.uri	http://hdl.handle.net/21.11130/00-1735-0000-0008-59C3-8
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-8993
dc.language.iso	eng	de
dc.publisher	Niedersächsische Staats- und Universitätsbibliothek Göttingen	de
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc	540	de
dc.title	Earth-Abundant Transition Metal-Catalyzed Electro-Reductive Cross-Electrophile Coupling Reactions and C–H Activation by Cobaltaelectro-Catalysis	de
dc.type	doctoralThesis	de
dc.contributor.referee	Ackermann, Lutz Prof. Dr.
dc.date.examination	2021-11-29
dc.description.abstracteng	Within the last decades, immense progresses have been made with transition metal-catalyzed cross-electrophile reactions and C–H activation reactions. The merger of electrocatalysis with such powerful methods have further enabled a series of more sustainable synthetical protocols for tackling issues such as, the alarming proliferation of CO2 in the atmosphere and the increased demand for more effective pharmaceuticals. This thesis illustrates the electro-catalytic use of earth-abundant and cost-effective cobalt catalyst through the efficient Carbon Capture and Utilization (CCU) strategy for the carboxylation reactions of allylic chlorides with atmospheric CO2. In addition, nickelaelectro-catalytic thiolation of alkyl bromides with electrophilic thiosulfonates have also been successfully described.	de
dc.contributor.coReferee	Das, Shoubhik Prof. Dr.
dc.contributor.thirdReferee	Tietze, Lutz Prof. Dr. Dr.
dc.contributor.thirdReferee	Stalke, Dietmar Prof. Dr.
dc.contributor.thirdReferee	Frauendorf, Holm Dr.
dc.contributor.thirdReferee	John, Michael Dr.
dc.subject.eng	electrochemical	de
dc.subject.eng	carbon dioxide	de
dc.subject.eng	carboxylation	de
dc.subject.eng	cobalt	de
dc.subject.eng	nickel	de
dc.subject.eng	C–H activation	de
dc.subject.eng	annulation	de
dc.subject.eng	thiolation	de
dc.subject.eng	transition metal catalysis	de
dc.subject.eng	sustainable	de
dc.identifier.urn	urn:nbn:de:gbv:7-21.11130/00-1735-0000-0008-59C3-8-3
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2021-12-20
dc.identifier.ppn	1782065954

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Fakultät für Chemie (inkl. GAUSS) [701]

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