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Synthese löslicher Aggregate des Indiums und Zinns

Modellverbindungen für metallorganische Katalysatoren und funktionalisierte Zinnsysteme

Synthesis of soluable Aggregates of Indium and Tin

Modelcompounds for metalorganic Catalysts and functionalized Tinsystems

by Jörg Janssen
Doctoral thesis
Date of Examination:2003-05-08
Date of issue:2004-06-30
Advisor:Prof. Dr. Dr. h.c. Herbert W. Roesky
Referee:Prof. Dr. Uwe Klingebiel
crossref-logoPersistent Address: http://dx.doi.org/10.53846/goediss-2238

 

 

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Abstract

English

Hydrolysis of metalorganic compounds often yields in catalytic activ species which are widely used in industriell processes, also there structurally nature is not known so far. This work was focused on the synthesis and structurally characterization of hydrolysis and ammonolysis products of metallorganic compounds of indium and tin. Herein will be discribed the synthesis of the first tinorganic acid and the first triaminostannane containing free NH-groups.
Keywords: Indium; tin; hydrolysis; ammonolysis; tinacid; triamminostannane

Other Languages

Hydrolyseprodukte von metallorganischen Verbindungen finden trotz ihrer strukturellen Ungeklärtheit vielfältigen Einsatz in der industriellen Produktion von Polymerprodukten. Diese Arbeit beschäftigt sich mit der Synthese und strukturellen Aufklärung von hydroxy- sowie aminosubstituierten metallorganischen Verbindungen des Indiums und Zinns. So konnten die Synthese und strukturelle Beschaffenheit der ersten Zinnsäure sowie des ersten Triaminostannanes realisiert werden.
Schlagwörter: Indium; Zinn; Hydrolyse; Ammonolyse; Zinnsäure; Triamminostannan; 540 Chemie
 

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