Electrochemical Dinitrogen Splitting and Nitride Transfer to Nitric Oxide with Rhenium Pincer Complexes

Alig, Lukas

dc.contributor.advisor	Schneider, Sven Prof. Dr.
dc.contributor.author	Alig, Lukas
dc.date.accessioned	2022-04-26T11:24:49Z
dc.date.available	2022-05-03T00:50:11Z
dc.date.issued	2022-04-26
dc.identifier.uri	http://resolver.sub.uni-goettingen.de/purl?ediss-11858/14006
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-9198
dc.language.iso	eng	de
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/
dc.subject.ddc	540	de
dc.title	Electrochemical Dinitrogen Splitting and Nitride Transfer to Nitric Oxide with Rhenium Pincer Complexes	de
dc.type	doctoralThesis	de
dc.contributor.referee	Schneider, Sven Prof. Dr.
dc.date.examination	2022-03-24	de
dc.description.abstracteng	The Haber-Bosch process for the synthesis of ammonia from nitrogen and hydrogen consumes large amounts of energy and additionally relies on fossil feedstocks for the production of hydrogen. Alternative approaches for the synthesis of nitrogenous chemicals and in particular nitrogen oxides as part of fertilizer are therefore highly desirable. In this thesis, the formation of nitrous oxide is reported upon initial (electro)chemical dinitrogen splitting into nucleophilic Rhenium nitride complexes and subsequent nitride-NO coupling. The overall comproportionation of N2 and NO to N2O is investigated with spectroscopic methods and theoretical calculations and revealed a formal "umpolung" of the Rhenium nitride complex upon initial NO coordination.	de
dc.contributor.coReferee	Meyer, Franc Prof. Dr.
dc.subject.eng	dinitrogen	de
dc.subject.eng	N2 fixation	de
dc.subject.eng	small molecule activation	de
dc.subject.eng	N-N bond formation	de
dc.subject.eng	Nitride Complex	de
dc.subject.eng	Electrochemical N2 Splitting	de
dc.subject.eng	DFT calculation	de
dc.subject.eng	nitric oxide	de
dc.subject.eng	nitrous oxide	de
dc.identifier.urn	urn:nbn:de:gbv:7-ediss-14006-1
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2022-05-03	de
dc.identifier.ppn	1800458029

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Fakultät für Chemie (inkl. GAUSS) [701]

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