Ramanspektroskopische Untersuchung der Esterfaltung in Überschallexpansionen, Oder: Wie man bei der Suche nach der Haarnadel im Esterhaufen fünf auf einmal findet

Gawrilow, Maxim

dc.contributor.advisor	Suhm, Martin A. Prof. Dr.
dc.contributor.author	Gawrilow, Maxim
dc.date.accessioned	2022-06-29T11:28:46Z
dc.date.available	2022-07-05T00:50:12Z
dc.date.issued	2022-06-29
dc.identifier.uri	http://resolver.sub.uni-goettingen.de/purl?ediss-11858/14130
dc.identifier.uri	http://dx.doi.org/10.53846/goediss-9313
dc.language.iso	deu	de
dc.subject.ddc	540	de
dc.title	Ramanspektroskopische Untersuchung der Esterfaltung in Überschallexpansionen, Oder: Wie man bei der Suche nach der Haarnadel im Esterhaufen fünf auf einmal findet	de
dc.type	doctoralThesis	de
dc.title.translated	Raman spectroscopic investigaton of the folding of esters in supersonic expansions, Or: While looking for a hairpin in an esterstack, how to find five at once	de
dc.contributor.referee	Suhm, Martin A. Prof. Dr.
dc.date.examination	2022-03-22	de
dc.description.abstracteng	The conformational preference of linear alkyl chains with an ester group in the center was investigated using Raman spectroscopy in supersonic expansions. Like alkanes, short esters prefer a stretched conformation, but beyond a critical chain length a hairpin-like conformation dominates due to intramolecular dispersive attraction. This turnover point was determined by combining experimental results with quantum chemical calculations. As part of the analysis, a rigorous characterisation of experimental Raman intensities for the setup was performed. For better comparability between calculated and experimental vibrational spectra a simulation of the rotational broadening was developed.	de
dc.contributor.coReferee	Behler, Jörg Prof. Dr.
dc.contributor.thirdReferee	Moshnyaga, Vasily Prof. Dr.
dc.contributor.thirdReferee	Mata, Ricardo Prof. Dr.
dc.contributor.thirdReferee	Schneider, Sven Prof. Dr.
dc.contributor.thirdReferee	Geil, Burkhard Prof. Dr.
dc.subject.eng	Raman spectroscopy	de
dc.subject.eng	Esters	de
dc.subject.eng	Supersonic Expansion	de
dc.subject.eng	Dispersive interaction	de
dc.subject.eng	Conformational preference	de
dc.subject.eng	Quantum chemical calculations	de
dc.identifier.urn	urn:nbn:de:gbv:7-ediss-14130-9
dc.affiliation.institute	Fakultät für Chemie	de
dc.subject.gokfull	Chemie (PPN62138352X)	de
dc.description.embargoed	2022-07-05	de
dc.identifier.ppn	1808732804

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Fakultät für Chemie (inkl. GAUSS) [701]

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