Browsing Fakultät für Chemie (inkl. GAUSS) by Referee "Bismuto, Alessandro Dr."
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Fixing the Conformation in Helicenes: Enantioselective Synthesis of [5]Helicenes and Synthesis of In-Fjord Substituted Expanded Helicenes
(2022-12-16)By combining the 3,3’-disubstituted BINOL-derived backbone and different cationic rests, a new family of α-cationic chiral phosphonites has been synthesized. Coordination to Au(I) afforded the corresponding precatalysts. ... -
Searching for more π-acceptor phosphines: From α-pyridiniophosphines to α-cationic phospholes
(2022-04-07)This thesis focuses on two classes of cationic phosphines. In the first part, the previously developed cationic pyridinio-phosphines were investigated further in respect to their coordination chemistry towards Ir and their ... -
Application of Asymmetric Gold-Catalyzed Hydroarylation in the Enantioselective Synthesis of Helicenes
(2022-04-07)A novel family of electron deficient, α-cationic ligands was synthesized, combining a chiral TADDOL-backbone with an electron withdrawing 1,2,3-triazolium moiety. Coordination to Au(I) gave the respective catalysts. Both ...